Selective hydrogenation over supported metal catalysts: from nanoparticles to single atoms

L Zhang, M Zhou, A Wang, T Zhang - Chemical reviews, 2019 - ACS Publications
Selective catalytic hydrogenation has wide applications in both petrochemical and fine
chemical industries, however, it remains challenging when two or multiple functional groups …

Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R Jin, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

The critical impacts of ligands on heterogeneous nanocatalysis: A review

L Lu, S Zou, B Fang - ACS Catalysis, 2021 - ACS Publications
Ligand utilization is a necessary and powerful technique for the colloidal synthesis of
nanoparticles (NPs) with controllable sizes and regulated morphologies. For catalysis …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

The role and fate of capping ligands in colloidally prepared metal nanoparticle catalysts

LM Rossi, JL Fiorio, MAS Garcia, CP Ferraz - Dalton Transactions, 2018 - pubs.rsc.org
Metal nanoparticles have received intense scientific attention in the field of catalysis. Precise
engineering of nanomaterials' size, shape and surface composition, including adsorbed …

Alloying gold with copper makes for a highly selective visible-light photocatalyst for the reduction of nitroaromatics to anilines

Q Xiao, S Sarina, ER Waclawik, J Jia, J Chang… - ACS …, 2016 - ACS Publications
Finely control of product selectivity is an essential issue in organic chemical production. In
the synthesis of functionalized anilines via reduction of the corresponding nitroarenes, the …

Strategies to improve hydrogen activation on gold catalysts

N Dimitratos, G Vilé, S Albonetti, F Cavani… - Nature Reviews …, 2024 - nature.com
Catalytic reactions involving molecular hydrogen are at the heart of many transformations in
the chemical industry. Classically, hydrogenations are carried out on Pd, Pt, Ru or Ni …

σ-H–H, σ-C–H, and σ-Si–H bond activation catalyzed by metal nanoparticles

JM Asensio, D Bouzouita, PWNM van Leeuwen… - Chemical …, 2019 - ACS Publications
Activation of H–H, Si–H, and C–H bonds through σ-bond coordination has grown in the past
30 years from a scientific curiosity to an important tool in the functionalization of …

Highly Selective and Solvent-Dependent Reduction of Nitrobenzene to N-Phenylhydroxylamine, Azoxybenzene, and Aniline Catalyzed by Phosphino-Modified …

S Doherty, JG Knight, T Backhouse, RJ Summers… - ACS …, 2019 - ACS Publications
Gold nanoparticles stabilized by phosphine-decorated polymer immobilized ionic liquids
(AuNP@ PPh2-PIILP) is an extremely efficient multiproduct selective catalyst for the sodium …

Gold–Ligand-Catalyzed Selective Hydrogenation of Alkynes into cis-Alkenes via H2 Heterolytic Activation by Frustrated Lewis Pairs

JL Fiorio, N López, LM Rossi - Acs Catalysis, 2017 - ACS Publications
The selective hydrogenation of alkynes to alkenes is an important synthetic process in the
chemical industry. It is commonly accomplished using palladium catalysts that contain …