Atropisomerism is a stereochemical behavior portrayed by three-dimensional molecules that
bear rotationally restricted σ bond. Akin to the well-represented point-chiral molecules …

Chirality has a key role in the synthesis of biomolecules and the development of life.
Although the effects of many chiral molecules or materials on biological processes have …

Transition-metal-catalyzed enantioselective C–H functionalization has become a powerful
strategy for the formation of C–C or C–X bonds, enabling the highly asymmetric synthesis of …

Direct catalytic transformation of C–H bonds to new functionalities has provided a powerful
strategy to synthesize complex molecular scaffolds in a straightforward way. Unstinting …

Although Suzuki–Miyaura cross-coupling is one of the most convenient and well-developed
cross-coupling reactions, its applications to the asymmetric version to deliver highly …

Enantioselective C− H activation has surfaced as a transformative toolbox for the efficient
assembly of chiral molecules. However, despite of major advances in rhodium and …

Conspectus Benzo-fused skeletons are ubiquitous in agrochemicals, medicines, natural
products, catalysts, and other organic function materials. The assembly of these skeletons in …

Enantioselective C–H functionalization for the synthesis of chiral molecules is a challenge in
organic synthesis. Although there are several methods for atroposelective C–H …

Chiral cyclopentadienyl rhodium (CpRh) complex‐catalyzed asymmetric C− H
functionalization reactions have witnessed a significant progress in organic synthesis. In …

We herein demonstrated an efficient method for the atroposelective construction of nine‐
membered carbonate‐bridged biaryls through vinylidene ortho‐quinone methide (VQM) …