Mechanical Regulation of Polymer Gels

C Xu, Y Chen, S Zhao, D Li, X Tang, H Zhang… - Chemical …, 2024 - ACS Publications
The mechanical properties of polymer gels devote to emerging devices and machines in
fields such as biomedical engineering, flexible bioelectronics, biomimetic actuators, and …

Supramolecular and molecular capsules, cages and containers

CJT Cox, J Hale, P Molinska, JEM Lewis - Chemical Society Reviews, 2024 - pubs.rsc.org
Stemming from early seminal notions of molecular recognition and encapsulation, three-
dimensional, cavity-containing capsular compounds and assemblies have attracted intense …

Oligo [2] catenane that is robust at both the microscopic and macroscopic scales

R Bai, Z Zhang, W Di, X Yang, J Zhao… - Journal of the …, 2023 - ACS Publications
Polycatenanes are extremely attractive topological architectures on account of their high
degrees of conformational freedom and multiple motion patterns of the mechanically …

Doubly threaded slide-ring polycatenane networks

LF Hart, WR Lenart, JE Hertzog, J Oh… - Journal of the …, 2023 - ACS Publications
Crosslinking in polymer networks leads to intrinsic structural inhomogeneities that result in
brittle materials. Replacing fixed covalent crosslinks with mobile ones in mechanically …

Molecular Ball Joints: Mechanochemical Perturbation of Bullvalene Hardy–Cope Rearrangements in Polymer Networks

PB Sun, MN Pomfret, MJ Elardo, A Suresh… - Journal of the …, 2024 - ACS Publications
The solution-state fluxional behavior of bullvalene has fascinated physical organic and
supramolecular chemists alike. Little effort, however, has been put into investigating …

Supramolecular Templation of Entanglements and Their Spectroscopic Detection in Polymer Elastomers

FS Wang, BJ Kruse, JC Dickenson… - …, 2024 - ACS Publications
Trapped entanglements─ topological cross-links among polymer chains in a network─ are
fundamental to polymers and have been correlated with mechanical properties like …

Supramolecular Templation of Entanglements in Organogels

EC Krist, BJ Kruse, JC Dickenson… - …, 2024 - ACS Publications
Polymer entanglements─ topological constraints to chain motion─ are fundamental
features of polymers, whose presence is believed to improve materials properties such as …

Topologically Controlled Syntheses of Unimolecular Oligo[n]catenanes

ND Colley, MA Nosiglia, SL Tran, GH Harlan… - ACS Central …, 2022 - ACS Publications
Catenanes are a well-known class of mechanically interlocked molecules that possess
chain-like architectures and have been investigated for decades as molecular machines and …

The effect of thread-like monomer structure on the synthesis of poly [n] catenanes from metallosupramolecular polymers

MM Tranquilli, BW Rawe, G Liu, SJ Rowan - Chemical Science, 2023 - pubs.rsc.org
The main-chain poly [n] catenane consists of a series of interlocked rings that resemble a
macroscopic chain-link structure. Recently, the synthesis of such intriguing polymers was …

Mechanically Interlocked [an]Daisy Chain Adhesives with Simultaneously Enhanced Interfacial Adhesion and Cohesion

Y Wang, G Liu, J Zhao, Z Zhang… - Angewandte Chemie …, 2024 - Wiley Online Library
Adhesives have been widely used to splice and repair materials to meet practical needs of
humanity for thousands of years. However, developing robust adhesives with balanced …