This review is focused on the analysis of current data on new methods of alkenylation of
arenes and heteroarenes with alkynes by transition metal catalyzed reactions …

Transition metal-catalyzed cyclization reactions of unsaturated substrates have become one
of the most important and useful methodologies for the preparation of heterocycles. To this …

We report herein the asymmetric coupling of flow‐generated unstabilized diazo compounds
and propargylated amine derivatives, using a new pyridinebis (imidazoline) ligand, a copper …

Indoles are important structural motifs that are commonly found in a diverse array of natural
products, pharmaceuticals, and other functional molecules. Consequently, the development …

A convenient method for the synthesis of indoles has been developed by the sequential
orchestration of the cross-coupling reaction of o-haloaniline and PIFA oxidation of the …

Abstract An enantioselective PdII/Brønsted acid‐catalyzed carbonylative carbocyclization of
enallenes ending with a cross‐dehydrogenative coupling (CDC) with a terminal alkyne was …

The electrophilic potential of diazirines has been utilized to obtain N-substituted diaziridines
that are directly hydrolyzed to produce monosubstituted hydrazines. The hydrazines can …

An olefin‐assisted palladium‐catalyzed oxidative carbocyclization–alkoxycarbonylation of
bisallenes to afford seven‐membered carbocycles has been established. This …

As part of natural products or biologically active compounds, the synthesis of nitrogen-
containing heterocycles is becoming incredibly valuable. Palladium is a transition metal that …

An efficient one‐pot method for the enzyme‐and ruthenium‐catalyzed enantioselective
transformation of α‐allenic alcohols into 2, 3‐dihydrofurans has been developed. The …