Bimetallic catalysis has emerged as an efficient strategy for the development of new
chemical reactions. Importantly, this strategy also provides a simple and powerful platform …

Conspectus Electron-deficient boron-based catalysts with metal-free but metallomimetic
characteristics provide a versatile platform for chemical transformations. However, their …

Cyclic organic carbonates represent a relevant class of chemicals that can be prepared from
CO2 by cycloaddition to epoxides. The application of efficient catalysts is crucial in allowing …

Positive cooperative binding, a phenomenon prevalent in biological processes, holds great
appeal for the design of highly sensitive responsive molecules and materials. It has been …

The development of efficient and straightforward methods for obtaining all optically active
isomers of structurally rigid spirocycles from readily available starting materials is of great …

Organometallic chemistry and its applications in homogeneous catalysis have been
dominated by mononuclear transition-metal complexes. The catalytic performance and …

The copolymerization of carbon dioxide (CO2) and epoxides to produce aliphatic
polycarbonates is a burgeoning technology for the large-scale utilization of CO2 and …

Multimetallic catalysis is based on the combined action of different metals in a chemical
transformation. It has witnessed rapidly increasing developments during the past decades in …

The stereodivergent synthesis of allene compounds bearing α, β‐adjacent central chiralities
has been realized via the Pd/Cu‐catalyzed dynamic kinetic asymmetric alkylation of racemic …

Bimetallic catalysis represents an alternative paradigm for coupling chemistry that
complements the more traditional single-site catalysis approach. In this perspective, recent …