As compared to porous network solids, including metal–organic frameworks, covalent–
organic frameworks, porous aromatic frameworks, and zeolites, porous molecular materials …

Molecules with permanent porosity in the solid state have been studied for decades.
Porosity in these systems is governed by intrinsic pore space, as in cages or macrocycles …

In coordination-driven self-assembly, 2, 2′: 6′, 2 ″-terpyridine (tpy) has gained extensive
attention in constructing supramolecular architectures on the basis of⟨ tpy-M-tpy⟩ …

Abstract Design and synthesis of metal–organic polyhedra (MOPs) with targeted geometries
from predetermined secondary building units (SBUs) is a long‐standing challenge in …

Ligand functionalization has been thoroughly leveraged to alter the properties of
paddlewheel-based coordination cages where, in the case of ligand-terminated cages …

The template-directed strategy has been extensively employed for the construction of
supramolecular architectures. However, with the increase in the size and complexity of these …

Despite recent advances toward understanding metallosupramolecular platforms, structural
classification remains a challenge because of the high multiplicity and diversity originating …

The number of studies concerning the permanent porosity of molecular materials, especially
porous organic cages (POCs) and porous coordination cages (PCCs), have increased …

Four cerium compounds–(HPy) 2 [CeCl6]· 2 (HPyCl)(Ce1-1),(HPy) 2 [CeCl6](Ce1-2),(HPy)
m [Ce38O56− x (OH) xCl50 (H2O) 12]· nH2O (Ce38), and (HPy) m [Ce52O80− x (OH) xCl59 …

A new series of 5-alkylamido isophthalic acid (ISA) derivatives with varying single and twin
alkyl chain lengths were designed and synthesized as potential supramolecular …