Stereoselective Synthesis of Glycosides via Tsuji–Trost Type Glycosylation Using 3,4‐Carbonate Galactals

YL Kim, JH Kim - The Chemical Record, 2024 - Wiley Online Library
Pd‐catalyzed stereoselective glycosylations using unsaturated sugar derivatives, glycals,
have been successfully achieved in recent years. This review focuses on approaches to …

Palladium-Catalyzed Regio- and Stereoselective Glycosylation of Azole Heterocycles Enables Access to Diverse Heterocyclic N-Glycosides

Y Xiong, Y Dai - Organic Letters, 2024 - ACS Publications
An efficient and practical glycosylation platform for synthesizing N-glycosides by leveraging
palladium catalysis is disclosed. This approach enables facile access to diverse heterocyclic …

Strained Ion Pair Interactions-Driven Anion-Assisted Concerted Addition of Ketoximes/Aldoximes and Hydroxamic Acids to Glycals

P Pradhan, A Biswas, MKV Rotta, PK Kancharla - Organic Letters, 2024 - ACS Publications
Oximes and hydroxylamides are notable for their role as coupling partners in organic
synthesis. However, their direct application as acceptors in O-glycosylation with glycal …

Facile and stereospecific synthesis of diverse β-N-glycosyl sulfonamide scaffolds via palladium catalysis

L Zhong, Q Wang, Y Wang, Y Cheng, Y Xiong… - Chemical …, 2023 - pubs.rsc.org
Glycosylation is an important strategy to improve the druggability of lead compounds. Here,
we present a palladium-catalysed stereospecific N-glycosylation of sulfonamides. This …

Palladium-Catalyzed Stereospecific Glycosylation Enables Divergent Synthesis of N–O-Linked Glycosides

Y Wang, Y Cheng, X Tao, W Yang, Z Zhou, Y Dai - Organic Letters, 2025 - ACS Publications
We present a versatile palladium-catalyzed glycosylation platform that enables facile access
to structurally diverse N–O-linked glycosides with constantly excellent regio-and …

Synthesis of N–O-Linked Glycosides via Stereospecific Pd-Catalyzed Reaction

M Lautens, A Dupeux - Synfacts, 2023 - thieme-connect.com
Significance: The Dai group reports a palladiumcatalyzed glycosylation between 3, 4-O-
carbonate glycals and acid-labile oximes under mild conditions. A set of-glycosyl oximes …