Photocatalyzed Oxygenation Reactions with Organic Dyes: State of the Art and Future Perspectives

M Forchetta, F Valentini, V Conte, P Galloni, F Sabuzi - Catalysts, 2023 - mdpi.com
Oxygen atom incorporation into organic molecules is one of the most powerful strategies to
increase their pharmacological activity and to obtain valuable intermediates in organic …

Electrosynthesis of N, N-dimethylformamide from market-surplus trimethylamine coupled with hydrogen production

M Jin, AZ Li, Y Wang, J Li, H Zhou, BJ Li, H Duan - Green Chemistry, 2023 - pubs.rsc.org
N, N-Dimethylformamide (DMF) is a universal solvent with wide applications across various
industries. Current industrial synthesis requires high temperature and high pressure, starting …

An organophotocatalytic late-stage N–CH 3 oxidation of trialkylamines to N-formamides with O 2 in continuous flow

MJP Mandigma, J Žurauskas, CI MacGregor… - Chemical …, 2022 - pubs.rsc.org
We report an organophotocatalytic, N–CH3-selective oxidation of trialkylamines in
continuous flow. Based on the 9, 10-dicyanoanthracene (DCA) core, a new catalyst (DCAS) …

Development of environmentally friendly dehydrogenative oxidation reactions using multifunctional heterogeneous catalysts

K Yamaguchi, X Jin, T Yatabe… - Bulletin of the Chemical …, 2022 - academic.oup.com
Our design strategies for multifunctional heterogeneous catalysts based on nanosized metal
oxides and metal nanoparticles as well as the development of several novel …

Electrochemically generated N-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

B Huang, C Yang, J Zhou, W Xia - Chemical Communications, 2020 - pubs.rsc.org
Reported herein is a straightforward protocol for approaching N-sulphonylamidines via an
electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between …

Copper–Nitroxyl-Catalyzed α-Oxygenation of Cyclic Secondary Amines Including Application to Late-Stage Functionalization

CM Hanneman, J Twilton, MN Hall… - Journal of the …, 2024 - ACS Publications
Cyclic secondary amines are prominent subunits in pharmaceutical compounds. Methods
for direct functionalization of N-unprotected/unsubstituted piperidines and related …

Computation Study on Copper-Catalyzed Aerobic Intramolecular Aminooxygenative C═ C Bond Cleavage to Imides: Different Roles of Mononuclear and Dinuclear …

Y Li, GC Ji, C Chao, S Bi, YY Jiang - ACS Catalysis, 2023 - ACS Publications
Cu-catalyzed aerobic reactions are a powerful protocol for the synthesis of value-added
chemicals based on the ideal oxidant O2. Despite the long research history, the mechanistic …

SBA-15 Supported 1-Methyl-2-azaadamanane N-Oxyl (1-Me-AZADO) as Recyclable Catalyst for Oxidation of Alcohol

Y Tian, X Guo, M Li, C Li, X Hu, L Jin, N Sun, B Hu… - Organic …, 2021 - ACS Publications
Herein, we designed and synthesized an SBA-15 supported 1-methyl-2-azaadamanane N-
oxyl (1-Me-AZADO) and investigated its catalytic performance for selective oxidation of …

Cu/N-Oxyl-catalyzed aerobic oxidative esterification to oxalic acid diesters from ethylene glycol via highly selective intermolecular alcohol oxidation

Y Morino, T Yatabe, K Suzuki, K Yamaguchi - Green Chemistry, 2022 - pubs.rsc.org
One of the ideal green esterification reactions is aerobic oxidative esterification using only a
stoichiometric amount of different alcohols via intermolecular selective alcohol oxidation …

Anderson-type polyoxometalate-based metal–organic framework as an efficient heterogeneous catalyst for selective oxidation of benzylic C–H bonds

HR Tan, X Zhou, T Gong, H You, Q Zheng, SY Zhao… - RSC …, 2024 - pubs.rsc.org
Oxidative transformation of benzylic C–H bonds into functional carbonyl groups under mild
conditions represents an efficient method for the synthesis of aromatic carboxylic acids and …