The history of the Point Defect Model for the passive state: A brief review of film growth aspects

DD Macdonald - Electrochimica Acta, 2011 - Elsevier
A review is presented of the history of the Point Defect Model (PDM) for the growth and
breakdown of passive films that form on the surfaces of reactive metals in contact with …

Passive films on stainless steels—chemistry, structure and growth

COA Olsson, D Landolt - Electrochimica acta, 2003 - Elsevier
The outstanding corrosion resistance of stainless steels results from the presence of a thin
oxide—'passive'—film on the metal surface, typically 1–3 nm thick. The characterisation of …

Point defect model for the corrosion of steels in supercritical water: Part I, film growth kinetics

Y Li, DD Macdonald, J Yang, J Qiu, S Wang - Corrosion Science, 2020 - Elsevier
Abstract A Point Defect Model has been developed to describe theoretically the corrosion of
metals and alloys in supercritical aqueous systems. The model, SCW_PDM, accounts for the …

Impact of reversed austenite on the pitting corrosion behavior of super 13Cr martensitic stainless steel

X Lei, Y Feng, J Zhang, A Fu, C Yin, DD Macdonald - Electrochimica Acta, 2016 - Elsevier
Many attempts in the past have been made to introduce the reversed austenite phase into
Super 13Cr martensitic stainless steel, in order to enhance its mechanical performance, but …

Electrochemical investigation and ab initio computation of passive film properties on copper in anaerobic sulphide solutions

D Kong, A Xu, C Dong, F Mao, K Xiao, X Li… - Corrosion …, 2017 - Elsevier
Electrochemical measurements based on the point defect model and ab initio calculations
were employed to investigate the properties of passive films formed on copper in anaerobic …

Effect of time on the characteristics of passive film formed on stainless steel

R Jiang, Y Wang, X Wen, C Chen, J Zhao - Applied Surface Science, 2017 - Elsevier
By potentiostatic polarisation for different time, passive films were formed on AISI 316SS.
Characteristics of these films were studied using electrochemical measurement and surface …

Initiation and repassivation of pitting corrosion of carbon steel in carbonated concrete pore solution

ZH Dong, W Shi, XP Guo - Corrosion Science, 2011 - Elsevier
The initiation, propagation, repassivation of metastable pits of Q345 carbon steel in Cl−
containing concrete pore solution were studied by electrochemical noise. The initiation rate …

Investigations on the passive and pitting behaviors of 17–4 PH martensitic stainless steel containing Al2O3 inclusions in chlorine environment

X Wang, H Luo, Q Zhao, H Cheng, Q Li, Z Pan… - Colloids and Surfaces A …, 2023 - Elsevier
The passive and pitting behaviors of 17–4 PH martensitic stainless steel containing Al 2 O 3
inclusions in chlorine environment were investigated. The electrochemical behavior was …

Degradation of SS316L bipolar plates in simulated fuel cell environment: Corrosion rate, barrier film formation kinetics and contact resistance

DD Papadias, RK Ahluwalia, JK Thomson… - Journal of Power …, 2015 - Elsevier
A potentiostatic polarization method is used to evaluate the corrosion behavior of SS316L in
simulated anode and cathode environments of polymer electrolyte fuel cells. A passive …

Some personal adventures in passivity—A review of the point defect model for film growth

DD Macdonald - Russian Journal of Electrochemistry, 2012 - Springer
A review is presented of the history of the development of the Point Defect Model (PDM) for
the growth and breakdown of passive films that form on the surfaces of reactive metals in …