Cofacial porphyrin organic cages. Metals regulating excitation electron transfer and CO 2 reduction electrocatalytic properties

X Liu, C Liu, X Song, X Ding, H Wang, B Yu, H Liu… - Chemical …, 2023 - pubs.rsc.org
Herein, we introduce a comprehensive study of the photophysical behaviors and CO2
reduction electrocatalytic properties of a series of cofacial porphyrin organic cages (CPOC …

Progress of porous organic cages in photo/electrocatalytic energy conversion and storage applications

RA Borse, YX Tan, D Yuan, Y Wang - Energy & Environmental Science, 2024 - pubs.rsc.org
Concerning and mimicking mother nature's creativity, the new class of porous organic cages
(POCs) materials have been one of the hot interests for/have inspired early and hardcore …

Molecular Co-Catalyst Confined within a Metallacage for Enhanced Photocatalytic CO2 Reduction

D Liu, H Ma, C Zhu, F Qiu, W Yu, LL Ma… - Journal of the …, 2024 - ACS Publications
The construction of structurally well-defined supramolecular hosts to accommodate
catalytically active species within a cavity is a promising way to address catalyst …

Covalent porous catalysts for electrochemical reduction of CO 2

S Lu, H Hu, H Sun, F Yang, H Zhu, M Du, Y Jin… - Green …, 2024 - pubs.rsc.org
The electrocatalytic CO2 reduction reaction (eCO2RR) stands out as a highly promising
approach to simultaneously resolving the issue of the elevated atmospheric CO2 …

Dynamic Covalent Self‐sorting in Molecular and Polymeric Architectures Enabled by Spiroborate Bond Exchange

Q Xu, X Wang, S Huang, Y Hu, SJ Teat… - Angewandte Chemie …, 2023 - Wiley Online Library
Self‐sorting is commonly observed in complex reaction systems, which has been utilized to
guide the formation of single major by‐design molecules. However, most studies have been …

Elaborate Modulating Binding Strength of Intermediates via Three‐component Covalent Organic Frameworks for CO2 Reduction Reaction

M Liu, CX Cui, S Yang, X Yang, X Li, J He… - Angewandte …, 2024 - Wiley Online Library
The catalytic performance for electrocatalytic CO2 reduction reaction (CO2RR) depends on
the binding strength of the reactants and intermediates. Covalent organic frameworks …

Supramolecular enhancement of electrochemical nitrate reduction catalyzed by cobalt porphyrin organic cages for ammonia electrosynthesis in water

L An, MR Narouz, PT Smith, P De La Torre… - Angewandte …, 2023 - Wiley Online Library
Abstract The electrochemical nitrate (NO3−) reduction reaction (NO3RR) to ammonia (NH3)
represents a sustainable approach for denitrification to balance global nitrogen cycles and …

Tailored Local Electronic Environment of Co‐N4 Sites in Cobalt Phthalocyanines for Enhanced CO2 Reduction Reaction

M Huang, B Chen, H Zhang, Y Jin, Q Zhi… - Small …, 2024 - Wiley Online Library
Atomically dispersed Co‐N4‐based catalysts have been recently emerging as one of the
most promising candidates for facilitating CO2 reduction reaction (CO2RR). The local …

[HTML][HTML] Tuning carbon dioxide electroreduction through selective facet exposure

L Chico-Mesa, E Herrero, RM Arán-Ais - Current Opinion in Chemical …, 2024 - Elsevier
The carbon dioxide reduction reaction (CO 2 RR) could reduce the atmospheric CO 2 and
store the excess energy obtained by renewable sources. However, proper catalysts are …

Light-Triggered Enhancement of Fluorescence Efficiency in Organic Cages

Z Yang, R Nandi, A Orieshyna… - The Journal of …, 2023 - ACS Publications
The fluorescence efficiency of excited molecules can be enhanced by many external factors.
Here, we showcase a surprising phenomenon whereby light is used as a gating source to …