Interfacial Spontaneous Reduction Strategy to Synthesize Low-Valent Pt Single-Atom Catalyst for Boosting Hydrosilylation

C Yang, J Tong, H Li, H Gao, G Wen, J Zhang… - ACS …, 2024 - ACS Publications
A heterogeneous N-coordinated Pt single-atom catalyst with low valence was synthesized
via an “interfacial spontaneous reduction (ISR)” strategy under mild conditions, using cheap …

Simply accessible platinum (ii) complexes enabling alkene hydrosilylation at ppm catalyst loadings

BP Maliszewski, E Casillo, P Lambert… - Chemical …, 2023 - pubs.rsc.org
An efficient olefin hydrosilylation protocol utilising Pt (II)–thioether-based pre-catalysts is
reported. These simple and readily available complexes exhibit excellent catalytic …

Recyclable and convenient-to-handle Pt/ethylene glycol catalytic system–an approach to sustainable hydrosilylation

IK Goncharova, RA Novikov, IP Beletskaya… - Journal of …, 2023 - Elsevier
This study presents a highly efficient and simple recyclable catalytic system for heterophase
hydrosilylation. This catalytic system consisting of a commercially available platinum …

White-Light initiated Mn2 (CO) 10/HFIP-Catalyzed anti-Markovnikov hydrosilylation of alkenes

IK Goncharova, SA Filatov, AP Drozdov… - Journal of …, 2024 - Elsevier
This study presents a highly efficient and mild method for radical hydrosilylation of alkenes.
The reaction proceeds under white-light, in the presence of Mn 2 (CO) 10 pre-catalyst and …

PtII−N‐Heterocyclic Carbene Complexes in Solvent‐Free Alkene Hydrosilylation

BP Maliszewski, TACA Bayrakdar… - … A European Journal, 2023 - Wiley Online Library
Herein, we report the catalytic activity of a series of platinum (II) pre‐catalysts, bearing N‐
heterocyclic carbene (NHC) ligands, in the alkene hydrosilylation reaction. Their structural …

Heterophase Pt/EG-catalyzed hydrosilylation in droplet microfluidics: Spectral monitoring and efficient 3D-printed reactors

AA Tereshchenko, IK Goncharova… - Chemical Engineering …, 2024 - Elsevier
Homogeneous Pt-catalyzed hydrosilylation is an industrially important process for the
synthesis of organosilanes. Reusable heterophase (biphase) Pt-catalysts can solve …

Recent Advances of Group 10 Transition Metal Hydrosilylation Catalysts

S Shimada - Perspectives of Hydrosilylation Reactions, 2023 - Springer
This chapter summarizes recent advances of group 10 transition metal hydrosilylation
catalysts from 2015 onward. Since the discovery of Speier's catalyst in 1957, homogeneous …

Platinum (II) Phenylpyridyl Schiff Base Complexes as Latent, Photoactivated, Alkene Hydrosilylation Catalysts

HG Lancaster, JC Goodall, SP Douglas… - ACS …, 2024 - ACS Publications
Photoactivated catalysts for the hydrosilylation of alkenes with silanes offer temporal control
in manufacturing processes that require silicone curing. We report the development of a …

Synthesis, X-ray structure, and catalytic activity in the hydrosilylation process of platinum complexes bearing Buchwald ligands

RY Lukin, AV Sukhov, AD Kachmarzhik… - …, 2023 - ACS Publications
The controlled reaction between [Pt2 (DVTMS) 3], where DVTMS represents 1, 3-divinyl-1, 1,
3, 3-tetramethyldisiloxane, and dialkylbiaryl phosphines (Buchwald ligands) 2-(di-tert …

Cyclobutadiene platinum complex as a new type of precatalyst for hydrosilylation of alkenes and alkynes

NV Shvydkiy, KV Rimskiy… - Applied Organometallic …, 2023 - Wiley Online Library
The readily available cyclobutadiene platinum complex [(C4Et4) PtCl2] catalyzes
hydrosilylation of alkenes and alkynes. The reaction typically proceeds at room temperature …