Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

First principles approach to the electronic structure, magnetic anisotropy and spin relaxation in mononuclear 3d-transition metal single molecule magnets

M Atanasov, D Aravena, E Suturina, E Bill… - Coordination Chemistry …, 2015 - Elsevier
In this review, a self-contained (although brief) introduction to electronic structure
calculations for single molecule magnet (SMM) properties is provided in conjunction with …

Heterometallic 3d–4f single-molecule magnets

LR Piquer, EC Sañudo - Dalton Transactions, 2015 - pubs.rsc.org
The promising potential applications, such as information processing and storage or
molecular spintronics, of single-molecule magnets (SMMs) have spurred on the research of …

Giant single-molecule magnets: a Mn84 torus and its supramolecular nanotubes

AJ Tasiopoulos, A Vinslava, W Wernsdorfer… - arXiv preprint cond-mat …, 2004 - arxiv.org
The discovery a decade ago that individual molecules can function as magnetizable
magnets provided a new,'bottom-up'approach to nanoscale magnetic materials, and such …

Quantum tunneling of magnetization in lanthanide single-molecule magnets, bis (phthalocyaninato) terbium and bis (phthalocyaninato)-dysprosium anions

N Ishikawa, M Sugita, W Wernsdorfer - arXiv preprint cond-mat/0506583, 2005 - arxiv.org
Magnetization versus field measurements were performed on single crystals of [(Pc) 2TbIII0.
02YIII0. 98]^ TBA+ and [(Pc) 2DyIII0. 02YIII0. 98]^ TBA+ (Pc: phthalocyaninato, TBA …

Nuclear spin driven quantum tunneling of magnetization in a new lanthanide single-molecule magnet: bis (phthalocyaninato) holmium anion

N Ishikawa, M Sugita… - Journal of the American …, 2005 - ACS Publications
The first measurements of magnetization hysteresis loops on a diluted single crystal of [(Pc)
2Ho]-⊙ TBA+ (Pc= phthalocyaninato, TBA= tetrabutylammonium) in the subkelvin …

Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets

A Swain, T Sharma, G Rajaraman - Chemical Communications, 2023 - pubs.rsc.org
Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets
(SMMs), as any future potential application in this class of molecules is directly correlated to …

A theoretical analysis of chemical bonding, vibronic coupling, and magnetic anisotropy in linear iron (II) complexes with single-molecule magnet behavior

M Atanasov, JM Zadrozny, JR Long, F Neese - Chemical Science, 2013 - pubs.rsc.org
The electronic structure and magnetic anisotropy of six complexes of high-spin FeII with
linear FeX2 (X= C, N, O) cores, Fe [N (SiMe3)(Dipp)] 2 (1), Fe [C (SiMe3) 3] 2 (2), Fe [N (H) …

Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2Fe(CN)6] Made of MnIII−FeIII−MnIII Trinuclear Single-Molecule Magnet with an ST = 9/2 Spin Ground …

M Ferbinteanu, H Miyasaka… - Journal of the …, 2005 - ACS Publications
The cyano-bridged trinuclear compound,(NEt4)[Mn2 (salmen) 2 (MeOH) 2Fe (CN)
6](1)(salmen2-= rac-N, N '-(1-methylethylene) bis (salicylideneiminate)), reported previously …

Structural motifs and topological representation of Mn coordination clusters

GE Kostakis, AM Ako, AK Powell - Chemical Society Reviews, 2010 - pubs.rsc.org
Polynuclear coordination clusters have become of particular interest in recent times as a
result of their relevance to bioinorganic chemistry and to the special area of molecule-based …