Application of transition metals in sulfoxidation reactions

Q Pu, M Kazemi, M Mohammadi - Mini-Reviews in Organic …, 2020 - ingentaconnect.com
Sulfoxides are key scaffolds in the synthesis of pharmaceutically active molecules. A large
number of sulfoxides are indispensable ingredients in the structure of most antibiotics …

Synthesis, spectra (FT-IR, NMR) investigations, DFT, FMO, MEP, NBO analysis and catalytic activity of MoO2 (VI) complex with ONO tridentate hydrazone Schiff base …

H Kargar, M Fallah-Mehrjardi… - Journal of Molecular …, 2021 - Elsevier
A new dioxomolybdenum (VI) complex has been successfully prepared by the reaction of an
ONO donor Schiff base, derived by condensing 4-amino-2-hydroxybenzohydrazide and 3 …

Selective synthesis of sulfoxides and sulfones from sulfides using silica bromide as the heterogeneous promoter and hydrogen peroxide as the terminal oxidant

B Maleki, S Hemmati, A Sedrpoushan, SS Ashrafi… - RSC Advances, 2014 - pubs.rsc.org
Silica bromide as a heterogeneous promoter and reagent is prepared from the reaction of
silica gel with PBr3 as a non-hydroscopic, filterable, cheap, and stable yellowish powder that …

Selectivity adjustment of SBA-15 based tungstate catalyst in oxidation of sulfides by incorporating a hydrophobic organic group inside the mesochannels

B Karimi, M Khorasani - ACS Catalysis, 2013 - ACS Publications
A novel heterogeneous catalyst system comprising tungstate ions embedded into the
hydrophobic mesochannels of SBA-15 was found to exhibit significant selectivity …

Selective hydrogen peroxide oxidation of sulfides to sulfoxides or sulfones with MWW-type titanosilicate zeolite catalyst under organic solvent-free conditions

Y Kon, T Yokoi, M Yoshioka, S Tanaka, Y Uesaka… - Tetrahedron, 2014 - Elsevier
Selective oxidation of sulfides to sulfoxides and sulfones with hydrogen peroxide under
organic solvent-free conditions was demonstrated by the MWW-type titanosilicate zeolite …

Oxidation of sulfides to sulfones with hydrogen peroxide in the presence of acetic acid and Amberlyst 15

VR Tumula, S Bondwal, P Bisht… - Reaction Kinetics …, 2012 - akjournals.com
The oxidation of thioanisole to its sulfone with hydrogen peroxide (H 2 O 2) in the presence
of acetic acid and Amberlyst 15 was investigated and found to be a simple and effective …

Ce(IV) immobilized on halloysite nanotube–functionalized dendrimer (Ce(IV)–G2): A novel and efficient dendritic catalyst for the synthesis of pyrido[3,2‐c]coumarin …

T Ataee‐Kachouei, M Nasr‐Esfahani… - Applied …, 2020 - Wiley Online Library
In this study, a new and stable Ce (IV) immobilized on halloysite nanotube–functionalized
dendrimer was designed, synthesized, and characterized using Fourier‐transform infrared …

Aluminum (III) triflate-catalyzed selective oxidation of glycerol to formic acid with hydrogen peroxide

K Kong, D Li, W Ma, Q Zhou, G Tang, Z Hou - Chinese Journal of Catalysis, 2019 - Elsevier
Glycerol is a by-product of biodiesel production and is an important readily available
platform chemical. Valorization of glycerol into value-added chemicals has gained immense …

Sodium sulfate–hydrogen peroxide–sodium chloride adduct: Selective protocol for the oxidative bromination, iodination and temperature dependent oxidation of …

EM Gayakwad, KP Patel, GS Shankarling - New Journal of Chemistry, 2019 - pubs.rsc.org
The regioselective bromination and iodination of unprotected aromatic primary amines using
enclathrated hydrogen peroxide as an oxidant under mild conditions has been developed …

New metal complexes supported on Fe3O4 magnetic nanoparticles as recoverable catalysts for selective oxidation of sulfides to sulfoxides

M Hajjami, S Kolivand - Applied Organometallic Chemistry, 2016 - Wiley Online Library
Fe3O4 nanoparticles were coated with aminopropyltriethoxysilane and subsequently
reacted with isatin to obtain imine‐bonded Fe3O4 nanoparticles. The addition of ZrOCl2⋅ …