Hydrogen production, transportation, utilization, and storage: Recent advances towards sustainable energy

NS Muhammed, AO Gbadamosi, EI Epelle… - Journal of Energy …, 2023 - Elsevier
Indubitably, hydrogen demonstrates sterling properties as an energy carrier and is widely
anticipated as the future resource for fuels and chemicals. Herein, an updated assessment …

Closed loops for hydrogen storage: Hydrolysis and regeneration of metal borohydrides

Y Zhu, J Li, L Yang, Z Huang, XS Yang, Q Zhou… - Journal of Power …, 2023 - Elsevier
Abstract Metal borohydrides (M (BH 4) n) are extensively studied due to their high hydrogen
storage capacities via hydrolysis. However, it is challenging to develop a closed loop of …

Closing the Loop for Hydrogen Storage: Facile Regeneration of NaBH4 from its Hydrolytic Product

Y Zhu, L Ouyang, H Zhong, J Liu, H Wang… - Angewandte …, 2020 - Wiley Online Library
Sodium borohydride (NaBH4) is among the most studied hydrogen storage materials
because it is able to deliver high‐purity H2 at room temperature with controllable kinetics via …

Preparation and regeneration of metal borohydrides for high-density hydrogen supply: Progress, challenges, and perspectives

J Zhang, H Li, X Xiao, L Ouyang - Journal of Alloys and Compounds, 2023 - Elsevier
Metal borohydrides have high theoretical hydrogen production/storage densities (> 10 wt%)
and offer an efficient real-time hydrogen supply for small and medium-sized mobile/portable …

Rehydrogenation of Sodium Borates to Close the NaBH4-H2 Cycle: A Review

HX Nunes, DL Silva, CM Rangel, AMFR Pinto - Energies, 2021 - mdpi.com
In 2007, the US Department of Energy recommended a no-go on NaBH4 hydrolysis for
onboard applications; however, the concept of a NaBH4-H2-PEMFC system has the …

Efficient synthesis of sodium borohydride: balancing reducing agents with intrinsic hydrogen source in hydrated borax

Y Zhu, L Ouyang, H Zhong, J Liu, H Wang… - ACS Sustainable …, 2020 - ACS Publications
Sodium borohydride (NaBH4) has been identified as one of the most promising hydrogen
storage materials; however, it is still challenging to produce NaBH4 with low cost and high …

Thermochemical Formation of Sodium Borohydride from Sodium Tetramethoxyborate

A Ibrahim, M Paskevicius, A Patel… - ACS Applied Energy …, 2024 - ACS Publications
Sodium borohydride (NaBH4) can be used as a hydrogen export material, but
thermochemical regeneration from NaBO2 is considered too costly to be feasible mainly due …

Synthesis of NaBH 4 as a hydrogen carrier from hydrated borax using a Mg–Al alloy

Y Zhu, H Zhong, L Ouyang, J Liu, H Wang… - Inorganic Chemistry …, 2022 - pubs.rsc.org
In this work, we reported an energy-saving and cost-efficient process for the (re) generation
of NaBH4 by ball milling hydrated borax (Na2B4O7· 10H2O) with a Mg–Al alloy under …

Breaking the passivation: Sodium borohydride synthesis by reacting hydrated borax with aluminum

Y Zhu, H Zhong, H Wang, L Ouyang… - … A European Journal, 2021 - Wiley Online Library
A significant obstacle in the large‐scale applications of sodium borohydride (NaBH4) for
hydrogen storage is its high cost. Herein, we report a new method to synthesize NaBH4 by …

Synthesis, characterisation and decomposition properties of manganese-based borohydrides for hydrogen storage

R Liu - 2012 - etheses.bham.ac.uk
In this work, a series of Mn-based borohydrides were synthesized by mechanochemical
milling of ABH\(_4\)-MnCl\(_2\)(where A= Li, Na, K) under argon. Samples prepared by …