Chemical sensing with 2D materials

C Anichini, W Czepa, D Pakulski, A Aliprandi… - Chemical Society …, 2018 - pubs.rsc.org
During the last decade, two-dimensional materials (2DMs) have attracted great attention due
to their unique chemical and physical properties, which make them appealing platforms for …

σ-Hole bond vs π-hole bond: a comparison based on halogen bond

H Wang, W Wang, WJ Jin - Chemical reviews, 2016 - ACS Publications
The σ-hole and π-hole are the regions with positive surface electrostatic potential on the
molecule entity; the former specifically refers to the positive region of a molecular entity …

Anion–π interactions suppress phase impurities in FAPbI3 solar cells

Z Huang, Y Bai, X Huang, J Li, Y Wu, Y Chen, K Li… - Nature, 2023 - nature.com
Achieving both high efficiency and long-term stability is the key to the commercialization of
perovskite solar cells (PSCs),. However, the diversity of perovskite (ABX3) compositions and …

The bright future of unconventional σ/π‐hole interactions

A Bauzá, TJ Mooibroek, A Frontera - ChemPhysChem, 2015 - Wiley Online Library
Non‐covalent interactions play a crucial role in (supramolecular) chemistry and much of
biology. Supramolecular forces can indeed determine the structure and function of a host …

Aromatic rings in chemical and biological recognition: energetics and structures

LM Salonen, M Ellermann… - Angewandte Chemie …, 2011 - Wiley Online Library
This review describes a multidimensional treatment of molecular recognition phenomena
involving aromatic rings in chemical and biological systems. It summarizes new results …

Putting anion–π interactions into perspective

A Frontera, P Gamez, M Mascal… - Angewandte Chemie …, 2011 - Wiley Online Library
Supramolecular chemistry is a field of scientific exploration that probes the relationship
between molecular structure and function. It is the chemistry of the noncovalent bond, which …

Binding mechanisms in supramolecular complexes

HJ Schneider - Angewandte Chemie International Edition, 2009 - Wiley Online Library
Forces to reckon with: Supramolecular complexes, such as the one shown, are normally
based on a combination of different interactions such as ion pairing, hydrogen bonds, and …

Anion-π interactions

BL Schottel, HT Chifotides, KR Dunbar - Chemical Society Reviews, 2008 - pubs.rsc.org
This tutorial review provides an overview of the theoretical and experimental investigations
that resulted in the recognition of anion-π interactions, ie, non-covalent forces between …

Anion− π interactions with fluoroarenes

M Giese, M Albrecht, K Rissanen - Chemical Reviews, 2015 - ACS Publications
Well-orchestrated noncovalent interactions are fundamental in chemical processes. 1 For
example, the assembly of complementary subunits to form functional aggregates is a …

The Cation–π Interaction in Small‐Molecule Catalysis

CR Kennedy, S Lin… - Angewandte Chemie …, 2016 - Wiley Online Library
Catalysis by small molecules (≤ 1000 Da, 10− 9 m) that are capable of binding and
activating substrates through attractive, noncovalent interactions has emerged as an …