The defining characteristic of a valence tautomeric (VT) transition in a metal complex with a
redox-active organic ligand is a stimulated intramolecular electron transfer between metal …

A number of photofunctional molecular compounds have been developed recently. Typical
examples of these are phototunable valence tautomeric compounds, which are now …

Valence tautomeric complexes combining electroactive ligands and transition metal ions are
known to exhibit two nearly degenerated electronic states (tautomers) with localized …

A family of dinuclear cobalt complexes with bridging bis (dioxolene) ligands derived from 3,
3, 3′, 3′-tetramethyl-1, 1′-spirobis (indane-5, 5′, 6, 6′-tetrol)(spiroH4) and ancillary …

We report on the first valence tautomeric dinuclear copper complex, featuring 2, 3, 5, 6‐
tetrakis (tetramethylguanidino) pyridine as a bridging redox‐active GFA (guanidino …

A series of dinuclear cobalt complexes of general formula [Co (Me n tpa)(diox-S-diox) Co
(Me n tpa)](PF6) 2· MeOH (n= 0, 2, 3) was prepared through the synthesis of the bis …

A Two-Step Valence Tautomeric Transition in a Dinuclear Cobalt Complex | Inorganic
Chemistry ACS ACS Publications C&EN CAS Find my institution Log In Inorganic Chemistry …

Complexes of the 4-(2 '-pyridyl)-1, 2, 3, 5-dithiadiazolyl radical bidentate ligand with bis (
hexafluoroacetylacetonato) manganese (II) and with bis (hexafluoroacetylacetonato) copper …

Valence tautomeric compounds involving nondixolene-type ligands are rare. The triple-
helicate copper (II) complex [CuII2 (L) 3](ClO4) 4· 3CH3CN (1) containing a redox-active N …

A diverse variety of thiazyl radicals is known. Intense study of these heterocycles continues
in the pursuit of molecule-based materials with novel, academically interesting, and …