Principles of mononucleating and binucleating ligand design
AL Gavrilova, B Bosnich - Chemical reviews, 2004 - ACS Publications
Although multimetallic complexes were known early in the development of modern
coordination chemistry, it is only over the past 30 years that special attention has been …
coordination chemistry, it is only over the past 30 years that special attention has been …
The catalytic mechanisms of binuclear metallohydrolases
Binuclear metallohydrolases are a structurally diverse group of enzymes that use binuclear
metal ion centers to catalyze the hydrolysis of amides and esters of carboxylic and …
metal ion centers to catalyze the hydrolysis of amides and esters of carboxylic and …
Metal complexes of organophosphate esters and open-framework metal phosphates: synthesis, structure, transformations, and applications
R Murugavel, A Choudhury, MG Walawalkar… - Chemical …, 2008 - ACS Publications
Phosphorus is a vital element both in living matter and in the Earth's crust. The human body
contains about 1% by weight of the element phosphorus, about 4/5 of this being present as …
contains about 1% by weight of the element phosphorus, about 4/5 of this being present as …
Kinetics and equilibrium adsorption of Cu (II), Cd (II), and Ni (II) ions by chitosan functionalized with 2 [-bis-(pyridylmethyl) aminomethyl]-4-methyl-6-formylphenol
Chitosan biopolymer chemically modified with the complexation agent 2 [-bis-(pyridylmethyl)
aminomethyl]-4-methyl-6-formylphenol (BPMAMF) was employed to study the kinetics and …
aminomethyl]-4-methyl-6-formylphenol (BPMAMF) was employed to study the kinetics and …
Spectroscopic and mechanistic studies of dinuclear metallohydrolases and their biomimetic complexes
An enhanced understanding of the metal ion binding and active site structural features of
phosphoesterases such as the glycerophosphodiesterase from Enterobacter aerogenes …
phosphoesterases such as the glycerophosphodiesterase from Enterobacter aerogenes …
Electronic Structure and Spectro-Structural Correlations of FeIIIZnII Biomimetics for Purple Acid Phosphatases: Relevance to DNA Cleavage and Cytotoxic Activity
Purple acid phosphatases (PAPs) are a group of metallohydrolases that contain a dinuclear
FeIIIMII center (MII= Fe, Mn, Zn) in the active site and are able to catalyze the hydrolysis of a …
FeIIIMII center (MII= Fe, Mn, Zn) in the active site and are able to catalyze the hydrolysis of a …
Binucleating hydrazonic ligands and their μ-hydroxodicopper (II) complexes as promising structural motifs for enhanced antitumor activity
JP Rada, BSM Bastos, L Anselmino… - Inorganic …, 2019 - ACS Publications
Very few inorganic antineoplastic drugs have entered the clinic in the last decades, mainly
because of toxicity issues. Because copper is an essential trace element of ubiquitous …
because of toxicity issues. Because copper is an essential trace element of ubiquitous …
New FeIIIZnII Complex Containing a Single Terminal Fe−Ophenolate Bond as a Structural and Functional Model for the Active Site of Red Kidney Bean Purple Acid …
The new heterodinuclear complex [FeIIIZnII (BPBPMP)(OAc) 2] ClO4 (1) with the
unsymmetrical N5O2 donor ligand 2-bis [{(2-pyridylmethyl)-aminomethyl}-6-{(2 …
unsymmetrical N5O2 donor ligand 2-bis [{(2-pyridylmethyl)-aminomethyl}-6-{(2 …
Accessing a synthetic Fe III Mn IV core to model biological heterobimetallic active sites
JL Lee, S Biswas, JW Ziller, EL Bominaar… - Chemical …, 2024 - pubs.rsc.org
Metalloproteins with dinuclear cores are known to bind and activate dioxygen, with a
subclass of these proteins having active sites containing FeMn cofactors and activities …
subclass of these proteins having active sites containing FeMn cofactors and activities …
Elucidating the roles of distinct chemical factors in the hydrolytic activities of hetero-and homonuclear synthetic analogues of binuclear metalloenzymes
In this study, hydrolytic activities of hetero-and homobinuclear metallovariants of an
asymmetric (I) or symmetric (II) ligand with the FeIII-ZnII, ZnII-ZnII, and CuII-CuII cores (ie …
asymmetric (I) or symmetric (II) ligand with the FeIII-ZnII, ZnII-ZnII, and CuII-CuII cores (ie …