Applications of the solvation parameter model in reversed-phase liquid chromatography

CF Poole, N Lenca - Journal of Chromatography A, 2017 - Elsevier
The solvation parameter model is widely used to provide insight into the retention
mechanism in reversed-phase liquid chromatography, for column characterization, and in …

Prediction of analyte retention time in liquid chromatography

PR Haddad, M Taraji, R Szücs - Analytical Chemistry, 2020 - ACS Publications
Scope and Layout of This Review. This review addresses the approaches used to predict
chromatographic retention time in a range of liquid chromatographic techniques, with a …

Predicting biophysical properties of small molecules from chromatographic measurements and the solvation parameter model

CF Poole, SN Atapattu - Journal of Chromatography A, 2024 - Elsevier
Biopartitioning processes are challenging to study and often require the sacrifice of multiple
animals. Therefore, it is more practical and cost-effective to correlate these processes with …

[HTML][HTML] A polemic on the use of reversed-phase liquid chromatography to determine descriptors for the solvation parameter model

CF Poole, SN Atapattu - Journal of Chromatography Open, 2023 - Elsevier
Revised descriptors for 74 varied compounds recommended for the characterization of
reversed-phase silica columns using the solvation parameter model are assigned by the …

Influence of solvent effects on retention of small molecules in reversed-phase liquid chromatography

CF Poole - Chromatographia, 2019 - Springer
Major obstacles to formulating a simple retention mechanism for reversed-phase liquid
chromatography are identified as the heterogeneous composition of the stationary phase …

Selectivity evaluation of core-shell silica columns for reversed-phase liquid chromatography using the solvation parameter model

CF Poole, SN Atapattu - Journal of Chromatography A, 2020 - Elsevier
For the selectivity evaluation of core-shell silica, siloxane-bonded reversed-phase columns
by the solvation parameter model a minimal set of thirty-five calibration compounds were …

Evaluation of the solvation parameter model as a quantitative structure-retention relationship model for gas and liquid chromatography

CF Poole - Journal of Chromatography A, 2020 - Elsevier
Abstract The Wayne State University (WSU) experimental descriptor database is utilized to
bench mark the current capability of the solvation parameter model for use as a quantitative …

Selection of calibration compounds for selectivity evaluation of siloxane-bonded silica columns for reversed-phase liquid chromatography by the solvation parameter …

CF Poole - Journal of Chromatography A, 2020 - Elsevier
For the faster evaluation of selectivity in reversed-phase liquid chromatography of siloxane-
bonded silica columns using the solvation parameter model a minimal set of calibration …

Additional investigations into the retention mechanism of hydrophilic interaction liquid chromatography by linear solvation energy relationships

G Schuster, W Lindner - Journal of Chromatography a, 2013 - Elsevier
In analogy to our previous publication, the hydrophilic interaction liquid chromatography
mechanism was examined in terms of hydrogen bonding, coulombic interactions and phase …

Solvatochromic parameters of imidazolium-, hydroxyammonium-, pyridinium-and phosphonium-based room temperature ionic liquids

JM Padro, M Reta - Journal of Molecular Liquids, 2016 - Elsevier
Solvatochromic solvent parameters of different room temperature ionic liquids based on the
imidazolium, hydroxyammonium, pyridinium and phosphonium cations, namely 1-butyl-3 …