Advances and challenges in single-molecule electron transport
Electronic transport properties of single-molecule junctions have been widely measured by
several techniques, including mechanically controllable break junctions, electromigration …
several techniques, including mechanically controllable break junctions, electromigration …
Large-area, ensemble molecular electronics: motivation and challenges
We review charge transport across molecular monolayers, which is central to molecular
electronics (MolEl), using large-area junctions (NmJ). We strive to provide a wide conceptual …
electronics (MolEl), using large-area junctions (NmJ). We strive to provide a wide conceptual …
Dynamic molecular switches with hysteretic negative differential conductance emulating synaptic behaviour
To realize molecular-scale electrical operations beyond the von Neumann bottleneck, new
types of multifunctional switches are needed that mimic self-learning or neuromorphic …
types of multifunctional switches are needed that mimic self-learning or neuromorphic …
Molecular diodes with rectification ratios exceeding 105 driven by electrostatic interactions
Molecular diodes operating in the tunnelling regime are intrinsically limited to a maximum
rectification ratio R of∼ 103. To enhance this rectification ratio to values comparable to …
rectification ratio R of∼ 103. To enhance this rectification ratio to values comparable to …
Charge transport through molecular ensembles: Recent progress in molecular electronics
This review focuses on molecular ensemble junctions in which the individual molecules of a
monolayer each span two electrodes. This geometry favors quantum mechanical tunneling …
monolayer each span two electrodes. This geometry favors quantum mechanical tunneling …
Transition from direct to inverted charge transport Marcus regions in molecular junctions via molecular orbital gating
Solid-state molecular tunnel junctions are often assumed to operate in the Landauer regime,
which describes essentially activationless coherent tunnelling processes. In solution, on the …
which describes essentially activationless coherent tunnelling processes. In solution, on the …
Bioengineering a single-protein junction
Bioelectronics moves toward designing nanoscale electronic platforms that allow in vivo
determinations. Such devices require interfacing complex biomolecular moieties as the …
determinations. Such devices require interfacing complex biomolecular moieties as the …
Systematic modulation of charge transport in molecular devices through facile control of molecule–electrode coupling using a double self-assembled monolayer …
We report a novel solid-state molecular device structure based on double self-assembled
monolayers (D-SAM) incorporated into the suspended nanowire architecture to form a “Au …
monolayers (D-SAM) incorporated into the suspended nanowire architecture to form a “Au …
Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers
Tunnelling currents through tunnelling junctions comprising molecules with cross-
conjugation are markedly lower than for their linearly conjugated analogues. This effect has …
conjugation are markedly lower than for their linearly conjugated analogues. This effect has …
Functional redox‐active molecular tunnel junctions
Y Han, CA Nijhuis - Chemistry–An Asian Journal, 2020 - Wiley Online Library
Redox‐active molecular junctions have attracted considerable attention because redox‐
active molecules provide accessible energy levels enabling electronic function at the …
active molecules provide accessible energy levels enabling electronic function at the …