Spin crossover iron complexes with spin transition near room temperature based on nitrogen ligands containing aromatic rings: from molecular design to functional …

Y Zhang, R Torres-Cavanillas, X Yan, Y Zeng… - Chemical Society …, 2024 - pubs.rsc.org
During last decades, significant advances have been made in iron-based spin crossover
(SCO) complexes, with a particular emphasis on achieving reversible and reproducible …

Control of electronic polarization via charge ordering and electron transfer: electronic ferroelectrics and electronic pyroelectrics

SQ Su, SQ Wu, S Kanegawa, K Yamamoto… - Chemical Science, 2023 - pubs.rsc.org
Ferroelectric, pyroelectric, and piezoelectric compounds whose electric polarization
properties can be controlled by external stimuli such as electric field, temperature, and …

Magnetoelectricity enhanced by electron redistribution in a spin crossover [FeCo] complex

X Zhang, WH Xu, W Zheng, SQ Su… - Journal of the …, 2023 - ACS Publications
Molecular-based magnetoelectric materials are among the most promising materials for next-
generation magnetoelectric memory devices. However, practical application of existing …

Mix and match–controlling the functionality of spin-crossover materials through solid solutions and molecular alloys

MA Halcrow - Dalton Transactions, 2024 - pubs.rsc.org
The influence of dopant molecules on the structure and functionality of spin-crossover (SCO)
materials is surveyed. Two aspects of the topic are well established. Firstly, isomorphous …

Simultaneous magneto-dielectric transitions in a fluorescent Hofmann-type coordination polymer

FF Yan, D Liu, R Cai, L Zhao, PD Mao, HY Sun… - Dalton …, 2023 - pubs.rsc.org
The design of magnetic molecular materials exhibiting multiple functions has garnered
significant interest owing to their potential applications in molecular switches, sensors, and …

Large Polarization Change Induced by Spin Crossover-Driven Fe (II) Ion Shuttling within a Tripodal Ligand

C Liu, SQ Wu, KG Gao, JS Hu, Y Li… - Journal of the …, 2025 - ACS Publications
The integration of spin crossover (SCO) magnetic switching and electric polarization
properties can engender intriguing correlated magnetic and electric phenomena. However …

Magnetoelectric Coupling in a Mn4Na–Organic Complex under Pulsed Magnetic Fields up to 73 T

JP Wampler, S Liu, DJ Mondal… - Journal of the …, 2024 - ACS Publications
Research on the magnetoelectric (ME) effect (or spin-electric coupling) in molecule-based
magnetic materials is a relatively nascent but promising topic. Molecule-based magnetic …

Symmetry breaking through molecular engineering to achieve “on–off–on” nonlinear optical switch in a [SnCl 6] 2− framework

Z Cai, Z Yinan, J Chen, X He, Z Zhang… - Chemical …, 2024 - pubs.rsc.org
The impact of molecular point groups on phase transition materials has been seldom
discussed. Two organic cations with different symmetries were incorporated into a [SnCl6] …

Activating a high-spin iron (II) complex to thermal spin-crossover with an inert non-isomorphous molecular dopant

MA Halcrow, HB Vasili, CM Pask, AN Kulak… - Dalton …, 2024 - pubs.rsc.org
[Fe (bpp) 2][ClO4] 2 (bpp= 2, 6-bis {pyrazol-1-yl} pyridine; monoclinic, C2/c) is high-spin
between 5–300 K, and crystallises with a highly distorted molecular geometry that lies along …

Synergetic spin crossover and fluorescence in a mononuclear iron (iii) complex

ZX Fan, KT Lian, PY Liao, ZY Ruan, ZP Ni… - Chemical …, 2024 - pubs.rsc.org
Two mononuclear iron (III) complexes (XEA)[Fe (azp) 2]· H2O (H2azp= 2, 2′-azodiphenol,
XEA= 2-fluoroethylammonium and 2-chloroethylammonium) are synthesized, which exhibit …