Evaluation of f-element borate chemistry
MA Silver, TE Albrecht-Schmitt - Coordination Chemistry Reviews, 2016 - Elsevier
The synthesis, structure elucidation, and spectroscopic measurements of a myriad of new, f-
element borates has revealed the unusual effects that this electron-rich oxoanion has on the …
element borates has revealed the unusual effects that this electron-rich oxoanion has on the …
Intrinsic Semiconducting Behavior in a Large Mixed‐Valent Uranium (V/VI) Cluster
M Zhang, C Liang, GD Cheng, J Chen… - Angewandte Chemie …, 2021 - Wiley Online Library
We disclose the intrinsic semiconducting properties of one of the largest mixed‐valent
uranium clusters,[H3O+][UV (UVIO2) 8 (μ3‐O) 6 (PhCOO) 2 (Py (CH2O) 2) 4 (DMF) 4](Ph …
uranium clusters,[H3O+][UV (UVIO2) 8 (μ3‐O) 6 (PhCOO) 2 (Py (CH2O) 2) 4 (DMF) 4](Ph …
A stable mixed-valent uranium (V, VI) organic framework as a fluorescence thermometer
D Gu, W Yang, H Chen, Y Yang, X Qin… - Inorganic Chemistry …, 2021 - pubs.rsc.org
The presence of stable U (V)-containing compounds is important for the study of
radionuclides. However, pentavalent uranium is prone to disproportionation, thus U (V) …
radionuclides. However, pentavalent uranium is prone to disproportionation, thus U (V) …
The Role of Alkalis in Orchestrating Uranyl‐Peroxide Reactivity Leading to Direct Air Capture of Carbon Dioxide
Spectator ions have known and emerging roles in aqueous metal‐cation chemistry,
respectively directing solubility, speciation, and reactivity. Here, we isolate and structurally …
respectively directing solubility, speciation, and reactivity. Here, we isolate and structurally …
Advances and perspectives of actinide chemistry from ex situ high pressure and high temperature chemical studies
High pressure high temperature (HP/HT) studies of actinide compounds allow the chemistry
and bonding of among the most exotic elements in the periodic table to be examined under …
and bonding of among the most exotic elements in the periodic table to be examined under …
U (V) Stabilization via Aliovalent Incorporation of Ln (III) into Oxo‐salt Framework
Pentavalent uranium compounds are key components of uranium's redox chemistry and
play important roles in environmental transport. Despite this, well‐characterized U (V) …
play important roles in environmental transport. Despite this, well‐characterized U (V) …
[U(H2O)2]{[(UO2)10O10(OH)2][(UO4)(H2O)2]}: A Mixed-Valence Uranium Oxide Hydrate Framework
A uranium oxide hydrate framework,[U (H2O) 2]{[(UO2) 10O10 (OH) 2][(UO4)(H2O)
2]}(UOF1), was synthesized hydrothermally using schoepite as a uranium precursor. The …
2]}(UOF1), was synthesized hydrothermally using schoepite as a uranium precursor. The …
A Mixed‐Valent Uranium Phosphonate Framework Containing UIV, UV, and UVI
It is shown that UVO2+ ions can reside at UVIO22+ lattice sites during mild reduction and
crystallization process under solvothermal conditions, yielding a complicated and rare mixed …
crystallization process under solvothermal conditions, yielding a complicated and rare mixed …
Synthesis and characterization of a uranium oxide hydrate framework with Sr (ii) ions: structural insights and mixed uranium valences
A mixed-valence uranium oxide hydrate framework with Sr2+ ions (UOF-Sr2) was
synthesized hydrothermally and characterized with multiple structural and spectroscopic …
synthesized hydrothermally and characterized with multiple structural and spectroscopic …
Uranyl oxide hydrate frameworks with lanthanide ions
Two uranyl oxide hydrate frameworks (UOFs) incorporating either Eu (III) or Gd (III) ions
were synthesized hydrothermally and structurally studied. The uranyl oxide hydroxide layers …
were synthesized hydrothermally and structurally studied. The uranyl oxide hydroxide layers …