Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage

M Zhang, DA Kitchaev, Z Lebens-Higgins… - Nature Reviews …, 2022 - nature.com
Intercalation chemistry has dominated electrochemical energy storage for decades, and
storage capacity worldwide has now reached the terawatt-hour level. State-of-the-art …

A Mechanistic Insight into the Oxygen Redox of Li‐Rich Layered Cathodes and their Related Electronic/Atomic Behaviors Upon Cycling

S Kang, D Choi, H Lee, B Choi, YM Kang - Advanced Materials, 2023 - Wiley Online Library
Li‐rich cathodes are extensively investigated as their energy density is superior to Li
stoichiometric cathode materials. In addition to the transition metal redox, this intriguing …

Oxygen release degradation in Li‐ion battery cathode materials: mechanisms and mitigating approaches

S Sharifi‐Asl, J Lu, K Amine… - Advanced Energy …, 2019 - Wiley Online Library
Widespread application of Li‐ion batteries (LIBs) in large‐scale transportation and grid
storage systems requires highly stable and safe performance of the batteries in prolonged …

A review on progress of lithium-rich manganese-based cathodes for lithium ion batteries

X Ji, Q Xia, Y Xu, H Feng, P Wang, Q Tan - Journal of Power Sources, 2021 - Elsevier
With the increasing demand for energy, layered lithium-rich manganese-based (Li-rich Mn-
based) materials have attracted extensive attention because of their high capacity and high …

Nanocomposite Engineering of a High‐Capacity Partially Ordered Cathode for Li‐Ion Batteries

E Lee, TU Wi, J Park, SW Park, MH Kim… - Advanced …, 2023 - Wiley Online Library
Understanding the local cation order in the crystal structure and its correlation with
electrochemical performances has advanced the development of high‐energy Mn‐rich …

Regulating anionic redox activity of lithium-rich layered oxides via LiNbO3 integrated modification

C Shen, Y Liu, L Hu, W Li, X Liu, Y Shi, Y Jiang, B Zhao… - Nano Energy, 2022 - Elsevier
Lithium-rich layered oxide cathodes suffer from severe interfacial degradation, capacity
attenuation and voltage fading which mainly result from poor reversibility of anionic redox. In …

First-principles computational insights into lithium battery cathode materials

S Zhao, B Wang, Z Zhang, X Zhang, S He… - Electrochemical Energy …, 2022 - Springer
Lithium-ion batteries (LIBs) are considered to be indispensable in modern society. Major
advances in LIBs depend on the development of new high-performance electrode materials …

Oxygen vacancies induced by charge compensation tailoring Ni-doped Co3O4 nanoflakes for efficient hydrogen evolution

W Zhong, C Yang, J Wu, W Xu, R Zhao, H Xiang… - Chemical Engineering …, 2022 - Elsevier
The electronic structure modulation of the catalysts shows great significance towards
hydrogen evolution reaction (HER). A charge compensation was realized by doping …

Highly reversible oxygen redox in layered compounds enabled by surface polyanions

Q Chen, Y Pei, H Chen, Y Song, L Zhen, CY Xu… - Nature …, 2020 - nature.com
Oxygen-anion redox in lithium-rich layered oxides can boost the capacity of lithium-ion
battery cathodes. However, the over-oxidation of oxygen at highly charged states …

Oxygen redox chemistry in rechargeable Li-ion and Na-ion batteries

MM Rahman, F Lin - Matter, 2021 - cell.com
Cationic redox-based oxide cathodes have formed the basis of alkali-ion batteries. The
limited energy density provided by cationic redox can be overcome by triggering oxygen …