Carbon dioxide-based functional polycarbonates: Metal catalyzed copolymerization of CO2 and epoxides

Y Wang, DJ Darensbourg - Coordination Chemistry Reviews, 2018 - Elsevier
Proof of principles studies by Inoue and coworkers in the late 1960s clearly illustrated the
poorly controlled coupling of CO 2 and epoxides to provide polycarbonates. These early …

Update and challenges in carbon dioxide‐based polycarbonate synthesis

J Huang, JC Worch, AP Dove, O Coulembier - ChemSusChem, 2020 - Wiley Online Library
The utilization of carbon dioxide as a comonomer to produce polycarbonates has attracted a
great deal of attention from both industrial and academic communities because it promises …

Green polycarbonates prepared by the copolymerization of CO2 with epoxides

M Taherimehr, PP Pescarmona - Journal of Applied Polymer …, 2014 - Wiley Online Library
Polycarbonates can be prepared by the copolymerization of epoxides with carbon dioxide
as an inexpensive, abundant, nontoxic, and renewable feedstock. This review covers the …

Synthesis of atactic and isotactic poly (1, 2-glycerol carbonate) s: degradable polymers for biomedical and pharmaceutical applications

H Zhang, MW Grinstaff - Journal of the American Chemical …, 2013 - ACS Publications
The synthesis and characterization of atactic and isotactic linear poly (benzyl 1, 2-glycerol
carbonate) s are reported. The poly (benzyl 1, 2-glycerol carbonate) s were obtained via the …

Mechanistic Understanding of Dinuclear Cobalt(III) Complex Mediated Highly Enantioselective Copolymerization of meso-Epoxides with CO2

Y Liu, WM Ren, C Liu, S Fu, M Wang, KK He… - …, 2014 - ACS Publications
The desymmetrization copolymerization of meso-epoxides with CO2 using chiral catalysts or
reagents is regarded as a valuable strategy for the synthesis of optically active …

Biocompatible shape memory blend for self-expandable stents with potential biomedical applications

Y Zheng, Y Li, X Hu, J Shen, S Guo - ACS applied materials & …, 2017 - ACS Publications
Biocompatible poly (propylene carbonate)(PPC)/polycaprolactone (PCL) shape memory
blends were fabricated using melt blending. The shape memory performance of these …

Body temperature-triggered shape-memory effect via toughening sustainable poly (propylene carbonate) with thermoplastic polyurethane: toward potential application …

B Zeng, Y Li, L Wang, Y Zheng, J Shen… - … Sustainable Chemistry & …, 2020 - ACS Publications
Shape-memory polymeric materials triggered by body temperature were fabricated via
toughening sustainable poly (propylene carbonate)(PPC) with thermoplastic polyurethane …

Synthesis and characterization of poly (glyceric acid carbonate): a degradable analogue of poly (acrylic acid)

H Zhang, X Lin, S Chin… - Journal of the American …, 2015 - ACS Publications
The synthesis and characterization of a degradable version of poly (acrylic acid), poly
(glyceric acid carbonate), are reported. Specifically, atactic and isotactic poly (benzyl …

Thermodynamic Constraints for the Utilization of CO2

K Müller, L Mokrushina, W Arlt - Chemie Ingenieur Technik, 2014 - Wiley Online Library
The production of chemical compounds from carbon dioxide could be a way to reduce this
major greenhouse gas and gain a cheap raw material base. A variety of potential reactions …

Comments on the depolymerization of polycarbonates derived from epoxides and carbon dioxide: A mini review

DJ Darensbourg - Polymer Degradation and Stability, 2018 - Elsevier
There are in general few examples where polymers can be effectively recycled to their
monomers. If this situation exists, the recycling of these monomers to polymeric materials …