Gold-catalyzed reactions of specially activated alkynes, allenes, and alkenes

D Campeau, DF León Rayo, A Mansour… - Chemical …, 2020 - ACS Publications
This review describes the gold-catalyzed reactions of specially activated alkynes, allenes,
and alkenes. Such species are characterized by the presence of either electron-donating or …

Divergent gold catalysis: unlocking molecular diversity through catalyst control

CC Chintawar, AK Yadav, A Kumar… - Chemical …, 2021 - ACS Publications
The catalyst-directed divergent synthesis, commonly termed as “divergent catalysis”, has
emerged as a promising technique as it allows chartering of structurally distinct products …

Gold‐catalyzed cross‐coupling reactions: an overview of design strategies, mechanistic studies, and applications

A Nijamudheen, A Datta - Chemistry–A European Journal, 2020 - Wiley Online Library
Transition‐metal‐catalyzed cross‐coupling reactions are central to many organic synthesis
methodologies. Traditionally, Pd, Ni, Cu, and Fe catalysts are used to promote these …

Cyclopentyl methyl ether: an elective ecofriendly ethereal solvent in classical and modern organic chemistry

U Azzena, M Carraro, L Pisano, S Monticelli… - …, 2019 - Wiley Online Library
Solvents represent one of the major contributions to the environmental impact of fine‐
chemical synthesis. As a result, the use of environmentally friendly solvents in widely …

Conceptual advances in the preparation and excited-state properties of neutral luminescent (C^ N) and (C^ C*) monocyclometalated gold (III) complexes

R Malmberg, K Venkatesan - Coordination Chemistry Reviews, 2021 - Elsevier
Luminescent cyclometalated complexes are indispensable in today's technologies and are
applied as emitters in organic light-emitting diode (OLED) devices, photocatalysts …

Carbophilic activation of π-systems via gold coordination: Towards regioselective access of intermolecular addition products

C Praveen - Coordination Chemistry Reviews, 2019 - Elsevier
The utilization of intermolecular addition of carbon–carbon π-bonded systems as atom-
economical approach is a topic of significant interest in synthetic organic chemistry. Apart …

Recent Developments in the Meyer‐Schuster Rearrangement

F Justaud, A Hachem, R Grée - European Journal of Organic …, 2021 - Wiley Online Library
Abstract The Meyer‐Schuster rearrangement is an efficient method to prepare α, β‐
unsatured carbonyl compounds starting from propargylic alcohols and this review presents …

Silver-Catalyzed C- to N-Center Remote Arene Migration

Y Ning, A Mekareeya, KR Babu, EA Anderson… - ACS Catalysis, 2019 - ACS Publications
The 1, 4-arene migration from a carbon to a nitrogen center, induced by iminyl radicals
generated from radical additions to vinyl azides, is reported. Two different modes of vinyl …

Copper-Catalyzed reductive ring-cleavage of isoxazoles: synthesis of fluoroalkylated enaminones and application for the preparation of celecoxib, deracoxib, and …

C Wan, JY Pang, W Jiang, XW Zhang… - The Journal of Organic …, 2021 - ACS Publications
We have identified a new reactivity of copper/diamine catalysis for the reductive ring-
cleavage of isoxazoles to yield fluoroalkylated enaminones. This protocol has the advantage …

Studies on gold (I) and gold (III) alcohol functionalised NHC complexes

HF Jónsson, A Orthaber, A Fiksdahl - Dalton Transactions, 2021 - pubs.rsc.org
Five pairs of novel chiral alcohol functionalised gold (I) and gold (III) NHC complexes
derived from chiral amino alcohols, were synthesized and characterised (NMR, IR, HRMS) …