Stabilizing an exotic dianionic tetrazine bridge in a Ln 2 metallocene

N Mavragani, AA Kitos, A Mansikkamäki… - Chemical …, 2024 - pubs.rsc.org
The unique electronic nature of the 1, 2, 4, 5-tetrazine or s-tetrazine (tz) ring has sparked
tremendous scientific interest over the last few years. Tetrazines have found numerous …

Intensity and lifetime ratiometric luminescent thermometer based on a Tb (iii) coordination polymer

AI Costa, RMR da Silva, LDG Botelho… - Dalton …, 2024 - pubs.rsc.org
A three-dimensional terbium (III) coordination polymer of formula [Tb (bttb) 0.5 (2, 5-pzdc)
0.5] n (1)[H4bttb= 1, 2, 4, 5-tetrakis (4′-carboxyphenyl) benzene and H2-2, 5-pzdc= 2, 5 …

Slow magnetic relaxation and luminescence properties in lanthanide (III)/anil complexes

D Maniaki, I Mylonas-Margaritis, J Mayans… - Dalton …, 2018 - pubs.rsc.org
The initial use of anils, ie bidentate Schiff bases derived from the condensation of anilines
with salicylaldehyde or its derivatives, in 4f-metal chemistry is described. The 1: 1 reactions …

[HTML][HTML] High content and dispersion of Gd in bimodal porous silica: T2 contrast agents under ultra-high magnetic fields

MD Garrido, N Puchol, J El Haskouri… - Microporous and …, 2022 - Elsevier
Abstract Silica-based UVM-7-type bimodal mesoporous materials with high gadolinium
content (∞≥ Si/Gd≥ 13) have been synthesized through a one-pot surfactant-assisted …

Mononuclear and binuclear lanthanide acetates with chelating and bridging triethanolamine ligands

PS Koroteev, AB Ilyukhin, NN Efimov, EV Belova… - Polyhedron, 2018 - Elsevier
The interaction of lanthanide acetates with triethanolamine in pyridine medium yields
mononuclear cationic complexes [Ln (teaH 3) 2 (MeCOO)](MeCOO) 2· 0.5 Py (teaH 3= N …

A supramolecular chain of dimeric Dy single molecule magnets decorated with azobenzene ligands

G Huang, X Yi, F Gendron, B Le Guennic… - Dalton …, 2019 - pubs.rsc.org
We report the synthesis, ab initio calculations, magnetic and optical characterization of a
DyIII-based dimeric compound named DyAZO. The dimers self-organize into a …

Mononuclear Lanthanide (III)-Salicylideneaniline Complexes: Synthetic, Structural, Spectroscopic, and Magnetic Studies

I Mylonas-Margaritis, D Maniaki, J Mayans… - Magnetochemistry, 2018 - mdpi.com
The reactions of hydrated lanthanide (III)[Ln (III)] nitrates and salicylideneaniline (salanH)
have provided access to two families of mononuclear complexes depending on the reaction …

Closing the Circle of the Lanthanide-Murexide Series: Single-Molecule Magnet Behavior and Near-Infrared Emission of the NdIII Derivative

G Huang, G Calvez, Y Suffren, C Daiguebonne… - Magnetochemistry, 2018 - mdpi.com
Up to now, even if murexide-based complexometric studies are performed with all 3d or 4f
ions, the crystal structures of the light-lanthanide derivatives of the lanthanide-murexide …

Thermogravimetric measurement of the equilibrium vapour pressure: Application to water and triethanolamine

I Zghal, J Farjas, J Camps, M Dammak, P Roura - Thermochimica Acta, 2018 - Elsevier
A model that describes the pure evaporation kinetics is introduced. This model takes into
account gas diffusion and convective gas transport; it describes the evaporation kinetics …

Asymmetric dinuclear lanthanide (III) complexes from the use of a ligand derived from 2-acetylpyridine and picolinoylhydrazide: synthetic, structural and magnetic …

D Maniaki, PS Perlepe, E Pilichos, S Christodoulou… - Molecules, 2020 - mdpi.com
A family of four Ln (III) complexes has been synthesized with the general formula [Ln2 (NO3)
4 (L) 2 (S)](Ln= Gd, Tb, Er, and S= H2O; 1, 2 and 4, respectively/Ln= Dy, S= MeOH, complex …