Searching for novel materials via 4f chemistry

C Sun, K Li, D Xue - Journal of Rare Earths, 2019 - Elsevier
Abstract 4f chemistry studies the chemical bonding characteristics of fifteen lanthanide (Ln)
elements in the periodic table and their wide applications in materials sciences and …

Topological control of metal–organic frameworks toward highly sensitive and selective detection of chromate and dichromate

ZJ Li, Y Ju, XL Wu, X Li, J Qiu, Y Li, ZH Zhang… - Inorganic Chemistry …, 2023 - pubs.rsc.org
Luminescent metal–organic frameworks (LMOFs) have been extensively used as sensitive
and selective sensors for carcinogenic chromium (VI) oxyanions. However, the correlation …

The duality of electron localization and covalency in lanthanide and actinide metallocenes

DE Smiles, ER Batista, CH Booth, DL Clark… - Chemical …, 2020 - pubs.rsc.org
Previous magnetic, spectroscopic, and theoretical studies of cerocene, Ce (C8H8) 2, have
provided evidence for non-negligible 4f-electron density on Ce and implied that charge …

Real-time and visual sensing devices based on pH-control assembled lanthanide-barium nano-cluster

M Liu, H Li, L Bai, K Zheng, Z Zhao, Z Chen… - Journal of Hazardous …, 2021 - Elsevier
Real-time and visual monitoring of pollutants in the air is of great importance since they are
usually cannot be seen, smelled, or touched. Lanthanide nano-cluster is a kind of …

Enhancing actinide (III) over lanthanide (III) selectivity through hard-by-soft donor substitution: exploitation and implication of near-degeneracy-driven covalency

B Sadhu, M Dolg - Inorganic chemistry, 2019 - ACS Publications
Soft donor ligands often provide higher selectivity for actinides (III) over chemically similar
lanthanides (III), eg, in the AmIII–EuIII pair. Frequently, the origin of such selectivity is …

Covalency in AnCl 3 (An= Th–No)

S Cooper, N Kaltsoyannis - Dalton Transactions, 2021 - pubs.rsc.org
The geometric and electronic structures of AnCl3 are studied computationally using scalar
relativistic, hybrid density functional theory (PBE0). The An–Cl bond lengths generally …

Americium Oxalate: An Experimental and Computational Investigation of Metal–Ligand Bonding

A Arteaga, AD Nicholas, LC Ducati… - Inorganic …, 2023 - ACS Publications
A novel actinide-containing coordination polymer,[Am (C2O4)(H2O) 3Cl](Am-1), has been
synthesized and structurally characterized. The crystallographic analysis reveals that the …

Pronounced pressure dependence of electronic transitions for americium compared to isomorphous neodymium and samarium mellitates

JM Sperling, E Warzecha, BE Klamm… - Inorganic …, 2020 - ACS Publications
The mellitate ion is relevant in spent nuclear fuel processing and is utilized as a surrogate
for studying the interactions of f elements with humic acids. A wealth of different coordination …

Perspectives of multiscale rare earth crystal materials

C Sun, D Xue - CrystEngComm, 2019 - pubs.rsc.org
Multiscale rare earth crystal materials hold great promise for a wide range of applications,
including bioimaging diagnosis, therapy, lighting, lasers, motors, and security. Rare earth …

Systematic comparison of the structure of homoleptic tetradentate N 2 O 2-type Schiff base complexes of tetravalent f-elements (M (iv)= Ce, Th, U, Np, and Pu) in solid …

T Radoske, R Kloditz, S Fichter, J März, P Kaden… - Dalton …, 2020 - pubs.rsc.org
A series of tetradentate N2O2-type Schiff base complexes with tetravalent 4f-and 5f-block
metals,[M (salpn) 2](H2salpn= N, N′-disalicylidene-1, 3-diaminopropane; M= Ce, Th, U …