Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

Enantioconvergent catalysis has expanded asymmetric synthesis to new methodologies
able to convert racemic compounds into a single enantiomer. This review covers recent …

Enantioselective C− H activation has surfaced as a transformative toolbox for the efficient
assembly of chiral molecules. However, despite of major advances in rhodium and …

Substantial advances in enantioconvergent C (sp3)–C (sp3) bond formation reactions have
been made in recent years through the use of transition-metal-catalyzed cross-coupling …

The formation of a new C–C bond at sp3-hybridized centers is highly desirable, as it opens
up a unique, unexplored chemical space. The revolutionary discoveries in this field meet the …

Catalytic asymmetric C–C bond formation with alkylcopper intermediates as carbon
nucleophiles is now textbook chemistry. Related chemistry with boron and silicon …

Synthesis of the C− C bonds of ketones relies upon one high‐availability reagent (carboxylic
acids) and one low‐availability reagent (organometallic reagents or alkyl iodides). We …

Abstract Radikal‐Radikal‐Kupplungen sind nahezu diffusionskontrollierte Prozesse. Daher
sind selektive Kreuzkupplungen zweier unterschiedlicher Radikale schwierig zu realisieren …

A nickel-catalyzed C (sp3)–C (sp3) cross-electrophile coupling between α-silylated alkyl
bromides and an allylic sulfone is reported. Instead of a metal as the stoichiometric …

We report a highly enantioselective intermolecular C− H bond silylation catalyzed by a
phosphoramidite‐ligated iridium catalyst. Under reagent‐controlled protocols …