Organoelement chemistry: Promising growth areas and challenges

GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

Recent progress in the chemistry of metal amidinates and guanidinates: syntheses, catalysis and materials

FT Edelmann - Advances in organometallic chemistry, 2013 - Elsevier
This review provides a comprehensive overview of the most recent progress in chemistry
and applications of metal complexes containing heteroallylic ligands such as amidinates …

Thermally Stable Ln (II) and Ca (II) Bis (benzhydryl) Complexes: Excellent Precatalysts for Intermolecular Hydrophosphination of C–C Multiple Bonds

AN Selikhov, GS Plankin, AV Cherkasov… - Inorganic …, 2019 - ACS Publications
A series of Ln (II) and Ca (II) bis (alkyl) complexes with bulky benzhydryl ligands,[(pt Bu-
C6H4) 2CH] 2M (L n)(M= Sm, L= DME, n= 2 (1); M= Sm, Yb, Ca, L= TMEDA, n= 1 (2, 3, 4) …

Metallacyclic yttrium alkyl and hydrido complexes: synthesis, structures and catalytic activity in intermolecular olefin hydrophosphination and hydroamination

AA Kissel, TV Mahrova, DM Lyubov… - Dalton …, 2015 - pubs.rsc.org
Metallacyclic neutral and ionic yttrium alkyl complexes coordinated by a dianionic ene-
diamido ligand ([2, 6-iPr2C6H3NC (Me) C (Me) NC6H3iPr2-2, 6]= L1)[L1] Y …

Twisted and Disconnected Chains: Flexible Linear Tetracuprous Arrays and a Decanuclear CuI Cluster as Blue- and Green/Yellow-Light Emitters

J Arras, A Calderón-Díaz, S Lebedkin… - Inorganic …, 2024 - ACS Publications
Defined arrays of transition metal ions embedded in tailored polydentate ligand scaffolds
allow for a systematic design of their physical properties. Such molecular strings of closed …

Ln (II) alkyl complexes: from elusive exotics to catalytic applications

DM Lyubov, AA Trifonov - Inorganic Chemistry Frontiers, 2021 - pubs.rsc.org
Ln( ii ) alkyl complexes: from elusive exotics to catalytic applications - Inorganic Chemistry
Frontiers (RSC Publishing) DOI:10.1039/D1QI00206F Royal Society of Chemistry View PDF …

Ligands with two monoanionic N, N‐binding sites: synthesis and coordination chemistry

R Kretschmer - Chemistry–A European Journal, 2020 - Wiley Online Library
Polytopic ligands have become ubiquitous in coordination chemistry because they grant
access to a variety of mono‐and polynuclear complexes of transition metals as well as rare …

Activation of Ene-Diamido Samarium Methoxide with Hydrosilane for Selectively Catalytic Hydrosilylation of Alkenes and Polymerization of Styrene: an Experimental …

J Li, C Zhao, J Liu, H Huang, F Wang, X Xu… - Inorganic …, 2016 - ACS Publications
Samarium methoxide incorporating the ene-diamido ligand L (DME) Sm (μ-OMe) 2Sm
(DME) L (1; L=[DipNC (Me) C (Me) NDip] 2–, Dip= 2, 6-i Pr2C6H3, and DME= 1, 2 …

Living 3, 4‐(Co) Polymerization of Isoprene/Myrcene and One‐Pot Synthesis of a Polyisoprene Blend Catalyzed by Binuclear Rare‐Earth Metal Amidinate Complexes

X Yu, M Li, J Hong, X Zhou… - Chemistry–A European …, 2019 - Wiley Online Library
Mononuclear amidinate yttrium complex C4H9C (NR) 2Y (o‐CH2C6H4NMe2) 2 (R= 2, 6‐
iPr2C6H3) and a series of binuclear rare‐earth metal complexes bearing a bridged …

Bis (amidinate) ligands in early lanthanide chemistry–synthesis, structures, and hydroamination catalysis

N Kazeminejad, D Munzel, MT Gamer… - Chemical …, 2017 - pubs.rsc.org
Bis (amidinate) ligands attached to rigid dibenzofuran and phenanthrene backbones have
been introduced into lanthanide chemistry for the first time. Depending on the ligand and on …