3d-Metal catalyzed N-and C-alkylation reactions via borrowing hydrogen or hydrogen autotransfer

T Irrgang, R Kempe - Chemical reviews, 2018 - ACS Publications
The conservation of our element resources is a fundamental challenge of mankind. The
development of alcohol refunctionalization reactions is a possible fossil carbon conservation …

Advances in one-pot synthesis through borrowing hydrogen catalysis

A Corma, J Navas, MJ Sabater - Chemical reviews, 2018 - ACS Publications
The borrowing hydrogen (BH) principle, also called hydrogen auto-transfer, is a powerful
approach which combines transfer hydrogenation (avoiding the direct use of molecular …

Borrowing hydrogen amination reactions: a complex analysis of trends and correlations of the various reaction parameters

E Podyacheva, OI Afanasyev, DV Vasilyev… - ACS …, 2022 - ACS Publications
Borrowing hydrogen or the hydrogen autotransfer amination is a powerful approach to
create single C–N bonds, starting from stable and readily available substrates: amines and …

Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation

Q Yang, Q Wang, Z Yu - Chemical Society Reviews, 2015 - pubs.rsc.org
Transition metal-catalyzed substitution of alcohols by N-nucleophiles (or N-alkylation of
amines and related compounds with alcohols) avoids the use of alkylating agents by means …

Bio-based amines through sustainable heterogeneous catalysis

M Pelckmans, T Renders, S Van de Vyver, BF Sels - Green Chemistry, 2017 - pubs.rsc.org
The production of amines from biomass is a growing field of interest. Particularly the
amination of bio-based alcohols receives a lot of attention. In this review, we discuss recent …

Organonitrogen chemicals from oxygen-containing feedstock over heterogeneous catalysts

Y Wang, S Furukawa, X Fu, N Yan - ACS Catalysis, 2019 - ACS Publications
Organonitrogen chemicals, such as amines, nitriles, amides, amino acids, and N-
heterocycles, are ubiquitous building blocks in chemical industry. Conventional …

Lignin amination valorization: heterogeneous catalytic synthesis of aniline and benzylamine from lignin-derived chemicals

Y Rong, N Ji, Z Yu, X Diao, H Li, Y Lei, X Lu… - Green …, 2021 - pubs.rsc.org
Lignin chemistry is regarded as one of the core components in the field of biomass catalytic
conversion. Over the past decade, the catalytic synthesis of value-added chemicals or …

Reusable Co-nanoparticles for general and selective N-alkylation of amines and ammonia with alcohols

Z Ma, B Zhou, X Li, RG Kadam, MB Gawande… - Chemical …, 2022 - pubs.rsc.org
A general cobalt-catalyzed N-alkylation of amines with alcohols by borrowing hydrogen
methodology to prepare different kinds of amines is reported. The optimal catalyst for this …

Identification of an active NiCu catalyst for nitrile synthesis from alcohol

Y Wang, S Furukawa, N Yan - ACS Catalysis, 2019 - ACS Publications
Development of heterogeneous catalysts for alcohol transformation into nitriles under
oxidant-free conditions is a challenge. Considering the C–H activation on α-carbon of …

N-Alkylation by Hydrogen Autotransfer Reactions

X Ma, C Su, Q Xu - Hydrogen transfer reactions: reductions and beyond, 2016 - Springer
Owing to the importance of amine/amide derivatives in all fields of chemistry, and also the
green and environmentally benign features of using alcohols as alkylating reagents, the …