Recent progress in functional nanomaterials towards the storage, separation, and removal of tritium

M Rethinasabapathy, SM Ghoreishian… - Advanced …, 2023 - Wiley Online Library
Tritium is a sustainable next‐generation prime fuel for generating nuclear energy through
fusion reactions to fulfill the increasing global energy demand. Owing to the scarcity–high …

Graphene-based composite membranes for isotope separation: challenges and opportunities

F Rehman, FH Memon, Z Bhatti, M Iqbal… - Reviews in Inorganic …, 2022 - degruyter.com
Graphene-based membranes have got significant attention in wastewater treatment,
desalination, gas separation, pervaporation, fuel cell, energy storage applications due to …

Hydrogen isotope separation using a metal–organic cage built from macrocycles

D He, L Zhang, T Liu, R Clowes… - Angewandte Chemie …, 2022 - Wiley Online Library
Porous materials that contain ultrafine pore apertures can separate hydrogen isotopes via
kinetic quantum sieving (KQS). However, it is challenging to design materials with suitably …

Platinum single atom catalysts for hydrogen isotope separation during hydrogen evolution reaction

J Xu, R Li, X Yan, Q Zhao, R Zeng, J Ba, Q Pan… - Nano Research, 2022 - Springer
Electrolysis of water is widely used for hydrogen isotope separation and the development of
hydrogen evolution reaction (HER) catalysts with high selectivity and activity is of key …

Structural resolution and mechanistic insight into hydrogen adsorption in flexible ZIF-7

RA Klein, S Shulda, PA Parilla, P Le Magueres… - Chemical …, 2021 - pubs.rsc.org
Flexible metal–organic frameworks offer a route towards high useable hydrogen storage
capacities with minimal swings in pressure and temperature via step-shaped adsorption and …

[HTML][HTML] The next generation of low tritium hydrogen isotope separation technologies for future fusion power plants

L Shere, AK Hill, TJ Mays, R Lawless, R Brown… - International Journal of …, 2023 - Elsevier
The separation of hydrogen isotopes is a vital step in preparing tritium and deuterium fuels
for future fusion power plants. This represents a fundamental challenge to fusion energy …

Highly Effective H2/D2 Separation within the Stable Cu(I)Cu(II)-BTC: The Effect of Cu(I) Structure on Quantum Sieving

X Hu, F Ding, R Xiong, Y An, X Feng… - … Applied Materials & …, 2023 - ACS Publications
Realizing ideal deuterium separation from isotopic mixtures remains a daunting challenge
because of their almost identical sizes, shapes, and physicochemical properties. Using the …

High D2/H2 selectivity performance in MOF-303 under ambient pressure for potential industrial applications

H Kim, S Jee, J Park, M Jung, R Muhammad… - Separation and …, 2023 - Elsevier
The commercial demand for D 2 is poised to increase significantly; however, the low natural
abundance and the energy-and capital-intensive industrial separation (ie, 24 K cryogenic …

High Efficiency of Na- and Ca-Exchanged Chabazites in D2/H2 Separation by Quantum Sieving

I Bezverkhyy, V Boyer, C Cabaud… - ACS Applied Materials & …, 2022 - ACS Publications
Quantum sieving is a promising approach for separation of hydrogen isotopes using porous
solids as sorbents at cryogenic temperatures (< 77 K). In the present work, we characterized …

Enhance Hydrogen Isotopes Separation by Alkali Earth Metal Dopant in Metal–Organic Framework

W Dong, J Yuan, J Tan, X Tang, W Liu… - The Journal of …, 2023 - ACS Publications
Kinetic quantum sieving (KQS) based on pore size and chemical affinity quantum sieving
(CAQS) based on adsorption site are two routes of porous materials to separate hydrogen …