Organometallic chemistry and its applications in homogeneous catalysis have been
dominated by mononuclear transition-metal complexes. The catalytic performance and …

With their mechanistic novelty and various modalities of reactivity, transition metal
unsaturated carbene (alkenylidene) complexes have emerged as versatile intermediates for …

The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

There is growing interest in the design of bimetallic cooperative complexes, which have
emerged due to their potential for bond activation and catalysis, a feature widely exploited …

Cluster complexes have attracted interest for decades due to their promise of drawing
analogies to metallic surfaces and metalloenzyme active sites, but only recently have …

Cycloaddition reactions provide direct and convergent routes to cycloalkanes, making them
valuable targets for the development of synthetic methods. Whereas six-membered rings are …

The syntheses of four new tunable homogeneous organic reductants based on a
tetraaminoethylene scaffold are reported. The new reductants have enhanced air stability …

Dienes have been of great interest to synthetic chemists as valuable substrates due to their
abundance and ease of synthesis. Their unique stereoelectronic properties enable broad …

Monodentate phosphine ligands are frequently employed in the Ni-catalyzed C–O
functionalization of aryl esters. However, the extensive body of preparative work on such …

Cooperatively bimetallic organic catalysis, coupling actions of two metal centers in a
catalytic organic transformation via co‐activation of a single molecule or synergistic …