After the discovery of DNA during the mid-20th century, a multitude of novel methodologies
have surfaced which exploit DNA for its various properties. One such recently developed …

The highly energetic photons of ultraviolet light drive electronic and rovibronic transitions in
all molecular species. This radiation is thus a prime tool for strongly selective spectroscopic …

The yields of stabilized Criegee intermediates (sCIs), CH2OO and RCHOO (C2H5CHOO,
C3H7CHOO, C4H9CHOO, and C5H11CHOO), produced from ozonolysis of asymmetrical 1 …

Molecular diagnostics are a primary tool of modern chemistry, enabling researchers to map
chemical reaction pathways and rates to better design and control chemical systems. Many …

Though there is a growing body of literature on the kinetics of CIs with simple carbonyls, CI
reactions with functionalized carbonyls such as hydroxyketones remain unexplored. In this …

Criegee intermediates, formed by alkene ozonolysis in the troposphere, can react with
volatile organic compounds (VOCs). The temperature-dependent kinetics of the reactions …

An online sampling and mass spectrometry (MS) detection method was developed to study
the alkylation of PCl 3 with methane at high temperature for synthesis of methyl-dichloride …

A novel range of stabilised Criegee intermediate (sCI) species with halogenated substituent
groups have been identified as products to the reaction between with gaseous ozone and …

Absolute line strength measurements of hydroperoxyl (HO 2) radical in the OO-stretching (ν
3) fundamental band have been performed by means of mid-infrared time-resolved dual …

We present the development of a new astrochemical research tool HILTRAC, the Highly
Instrumented Low Temperature ReAction Chamber. The instrument is based on a pulsed …