Halide photoredox chemistry is of both practical and fundamental interest. Practical
applications have largely focused on solar energy conversion with hydrogen gas, through …

The utilization of visible light to mediate chemical reactions in fluid solutions has
applications that range from solar fuel production to medicine and organic synthesis. These …

Efficient excited-state electron transfer between an iron (III) photosensitizer and organic
electron donors was realized with green light irradiation. This advance was enabled by the …

Ruthenium (II) polypyridine complexes are among the most popular sensitizers in
photocatalysis, but they face some severe limitations concerning accessible excited-state …

The cage escape yield, ie, the separation of the geminate radical pair formed immediately
after bimolecular excited-state electron transfer, was studied in 11 solvents using six Fe (III) …

Transition-metal photocatalysts capable of oxidizing chloride are rare yet serve as an
attractive means to controllably generate chlorine atoms, which have continued to garner the …

The standard one-electron reduction potentials of halogen atoms, E°′(X•/–), and many
other radical or unstable species, are not accessible through standard electrochemical …

Single-crystal-to-single-crystal (SCSC) transformation has been demonstrated to provide an
ideal platform to explore the formation process of chemical bonds, which is conducive to …

Conspectus Iodide redox chemistry is intimately coupled with the formation and breaking of
chemical bonds that are relevant to emerging solar energy technologies. In this Account …

In this Viewpoint article, we describe an approach to enhance photosensitized
homogeneous photocatalysis of the CO2 reduction reaction by leveraging ion-pairing …