Pore chemistry of metal–organic frameworks

Z Ji, H Wang, S Canossa, S Wuttke… - Advanced Functional …, 2020 - Wiley Online Library
The pores in metal–organic frameworks (MOFs) can be functionalized by placing chemical
entities along the backbone and within the backbone. This chemistry is enabled by the …

The chemistry and applications of flexible porous coordination polymers

N Behera, J Duan, W Jin, S Kitagawa - EnergyChem, 2021 - Elsevier
Since the late 1990s, much progress has been made in the field of the chemistry of flexible
porous coordination polymers (PCPs). Various PCP architectures have been recognized …

An elastic metal–organic crystal with a densely catenated backbone

W Meng, S Kondo, T Ito, K Komatsu, J Pirillo, Y Hijikata… - Nature, 2021 - nature.com
What particular mechanical properties can be expected for materials composed of
interlocked backbones has been a long-standing issue in materials science since the first …

Mechanically interlocked materials. Rotaxanes and catenanes beyond the small molecule

S Mena-Hernando, EM Pérez - Chemical Society Reviews, 2019 - pubs.rsc.org
A mechanical bond presents a combination of the best features of covalent and
supramolecular chemistries (stability and structural integrity), plus a unique dynamic nature …

Towards artificial molecular factories from framework-embedded molecular machines

S Krause, BL Feringa - Nature Reviews Chemistry, 2020 - nature.com
Controlling cooperativity, synchronization, amplification and translation of intermolecular
and intramolecular dynamics over different length scales for applications in stimuli …

Catenanes: fifty years of molecular links

G Gil‐Ramírez, DA Leigh… - Angewandte Chemie …, 2015 - Wiley Online Library
Half a century after Schill and Lüttringhaus carried out the first directed synthesis of a [2]
catenane, a plethora of strategies now exist for the construction of molecular Hopf links …

Cuprous oxide (Cu2O) crystals with tailored architectures: A comprehensive review on synthesis, fundamental properties, functional modifications and applications

S Sun, X Zhang, Q Yang, S Liang, X Zhang… - Progress in Materials …, 2018 - Elsevier
Better understanding the crystal-facet engineering of a crystal with tailored architecture has
demonstrated a significant implication for rational design and synthesis of promising micro …

Flexibility in metal–organic frameworks: a fundamental understanding

SK Elsaidi, MH Mohamed, D Banerjee… - Coordination Chemistry …, 2018 - Elsevier
Expansion and contraction of structurally flexible Metal–Organic Frameworks (MOFs) or
Porous Coordination Polymers (PCPs) have been extensively studied from different …

Porous molecular solids and liquids

AI Cooper - ACS central science, 2017 - ACS Publications
Until recently, porous molecular solids were isolated curiosities with properties that were
eclipsed by porous frameworks, such as metal–organic frameworks. Now molecules have …

The story of the little blue box: a tribute to Siegfried Hünig

XY Chen, H Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
The tetracationic cyclophane, cyclobis (paraquat‐p‐phenylene), also known as the little blue
box, constitutes a modular receptor that has facilitated the discovery of many host–guest …