Spin-vibronic mechanism for intersystem crossing

TJ Penfold, E Gindensperger, C Daniel… - Chemical …, 2018 - ACS Publications
Intersystem crossing (ISC), formally forbidden within nonrelativistic quantum theory, is the
mechanism by which a molecule changes its spin state. It plays an important role in the …

Recent advances in organic thermally activated delayed fluorescence materials

Z Yang, Z Mao, Z Xie, Y Zhang, S Liu, J Zhao… - Chemical Society …, 2017 - pubs.rsc.org
Organic materials that exhibit thermally activated delayed fluorescence (TADF) are an
attractive class of functional materials that have witnessed a booming development in recent …

Highly efficient luminescence from space-confined charge-transfer emitters

X Tang, LS Cui, HC Li, AJ Gillett, F Auras, YK Qu… - Nature Materials, 2020 - nature.com
Abstract Charge-transfer (CT) complexes, formed by electron transfer from a donor to an
acceptor, play a crucial role in organic semiconductors. Excited-state CT complexes, termed …

High-efficiency electroluminescence and amplified spontaneous emission from a thermally activated delayed fluorescent near-infrared emitter

DH Kim, A D'aléo, XK Chen, ADS Sandanayaka… - Nature …, 2018 - nature.com
Near-infrared organic light-emitting diodes and semiconductor lasers could benefit a variety
of applications including night-vision displays, sensors and information-secured displays …

The importance of vibronic coupling for efficient reverse intersystem crossing in thermally activated delayed fluorescence molecules

J Gibson, AP Monkman, TJ Penfold - ChemPhysChem, 2016 - Wiley Online Library
Factors influencing the rate of reverse intersystem crossing (krISC) in thermally activated
delayed fluorescence (TADF) emitters are critical for improving the efficiency and …

Acceptor–donor–acceptor‐type orange–red thermally activated delayed fluorescence materials realizing external quantum efficiency over 30% with low efficiency roll …

D Karthik, YH Jung, H Lee, S Hwang… - Advanced …, 2021 - Wiley Online Library
Two new orange–red thermally activated delayed fluorescence (TADF) materials, PzTDBA
and PzDBA, are reported. These materials are designed based on the acceptor–donor …

Cu (I) complexes–Thermally activated delayed fluorescence. Photophysical approach and material design

R Czerwieniec, MJ Leitl, HHH Homeier… - Coordination Chemistry …, 2016 - Elsevier
Cu (I) complexes often show transitions of distinct metal-to-ligand charge transfer (MLCT)
character. This can lead to small energy separations between the lowest singlet S 1 and …

A review of fused-ring carbazole derivatives as emitter and/or host materials in organic light emitting diode (OLED) applications

S Oner, MR Bryce - Materials Chemistry Frontiers, 2023 - pubs.rsc.org
This review focuses on fused-ring carbazole derivatives, their molecular design, electronic
and photophysical properties, and in particular their applications as the emitter and/or the …

Versatile indolocarbazole‐isomer derivatives as highly emissive emitters and ideal hosts for thermally activated delayed fluorescent OLEDs with alleviated efficiency …

D Zhang, X Song, M Cai, H Kaji, L Duan - Advanced Materials, 2018 - Wiley Online Library
Maintaining high efficiency at high brightness levels is an exigent challenge for real‐world
applications of thermally activated delayed fluorescent organic light‐emitting diodes (TADF …

Probing polaron-induced exciton quenching in TADF based organic light-emitting diodes

M Hasan, S Saggar, A Shukla, F Bencheikh… - Nature …, 2022 - nature.com
Polaron-induced exciton quenching in thermally activated delayed fluorescence (TADF)-
based organic light-emitting diodes (OLEDs) can lead to external quantum efficiency (EQE) …