The catalytic dicarbofunctionalization of unsaturated π bonds represents a powerful platform
for the rapid construction of complex motifs. Despite remarkable progress, novel and efficient …

Nickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a
powerful tool for forging two C–C bonds in a single reaction. Building upon the powerful …

An asymmetric three-component carbosulfonylation of alkenes is presented here. The
reaction, involving the simultaneous formation of a C–C and a C–S bond across the π …

Catalytic functionalization of alkynes with organoboron reagents provides a straightforward
access to stereochemically defined multisubstituted alkenes, which are structural motifs …

Transformation of sterically hindered tertiary alkyl electrophiles under nickel-catalyzed
conditions to forge C (sp3)–C bonds and simultaneously create challenging all-carbon …

The N-heterocyclic carbene-catalyzed radical relay enables the vicinal alkylacylation of
styrenes, acrylates and acrylonitrile using aldehydes and tertiary alkyl carboxylic acid …

A nickel-catalyzed, enantioselective, three-component fluoroalkylarylation of unactivated
alkenes with aryl halides and perfluoroalkyl iodides has been described. This cross …

In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective
catalytic methods powered by electricity remain rare. In this work, we report the development …

Migration of metals along a carbon chain is triggered by two of the most common
organometallic elementary steps–β-hydride (β-H) elimination and alkene hydrometallation …

A nickel-catalyzed conjunctive cross-coupling of simple alkenyl amides with aryl iodides and
aryl boronic esters is reported. The reaction is enabled by an electron-deficient olefin (EDO) …