2D Self-assembled molecular networks and on-surface reactivity under nanoscale lateral confinement

L Verstraete, S De Feyter - Chemical Society Reviews, 2021 - pubs.rsc.org
Supramolecular self-assembly at surfaces provides a pathway for building chemically
customized interfaces. Over the last three decades, research on the role of key parameters …

Metalloporphyrins as building blocks for quantum information science

F Santanni, A Privitera - Advanced Optical Materials, 2024 - Wiley Online Library
The intrinsic quantum nature of molecules opens exciting opportunities for developing the
field of quantum information science. In this context, porphyrins stand out as ideal building …

Bending a photonic wire into a ring

H Gotfredsen, JR Deng, JM Van Raden, M Righetto… - Nature Chemistry, 2022 - nature.com
Natural light-harvesting systems absorb sunlight and transfer its energy to the reaction
centre, where it is used for photosynthesis. Synthetic chromophore arrays provide useful …

Molecular Quantum Rings Formed from a -Conjugated Macrocycle

CJ Judd, AS Nizovtsev, R Plougmann, DV Kondratuk… - Physical Review Letters, 2020 - APS
The electronic structure of a molecular quantum ring (stacks of 40-unit cyclic porphyrin
polymers) is characterized via scanning tunneling microscopy and scanning tunneling …

Structural characterisation of molecular conformation and the incorporation of adatoms in an on-surface Ullmann-type reaction

CJ Judd, FLQ Junqueira, SL Haddow… - Communications …, 2020 - nature.com
The on-surface synthesis of covalently bonded materials differs from solution-phase
synthesis in several respects. The transition from a three-dimensional reaction volume to …

Self-assembly of a strapped linear porphyrin oligomer on HOPG

A Bellamy-Carter, C Roche, HL Anderson… - Scientific Reports, 2021 - nature.com
Polymeric structures based on porphyrin units exhibit a range of complex properties, such as
nanoscale charge transport and quantum interference effects, and have the potential to act …

Anchoring and Reacting On-Surface to Achieve Programmability

X Li, H Ge, R Xue, M Wu, L Chi - JACS Au, 2021 - ACS Publications
On-surface synthesis has developed into a modern method to fabricate low-dimensional
molecular nanostructures with atomic precision. It impresses the chemistry community …

On-surface synthesis of thiophene-containing large-sized organometallic macrocycles on the Ag (111) surface

X Zhang, Q Shen, H Ding, X Chen, H Yang… - The Journal of …, 2021 - ACS Publications
On-surface synthesis is exhibited as a promising “bottom-up” approach for fabricating
numerous macromolecular nanostructures. Compared to noncyclic architectures …

Host guest chemistry and supramolecular doping in triphenylamine-based covalent frameworks on Au (111)

C Steiner, L Fromm, J Gebhardt, Y Liu, A Heidenreich… - Nanoscale, 2021 - pubs.rsc.org
The post-synthetic modification of covalent organic frameworks (COFs) via host–guest
chemistry is an important method to tailor their electronic properties for applications. Due to …

Quantum chemical support on the two-dimensional assembly of porphyrin rings in the application of energy-storage devices

R Suresh, V Subramaniam - The Journal of Physical Chemistry C, 2020 - ACS Publications
Metal-ion batteries are the revolutionary gadgets of the present decade which still need
improvement in efficiency and stability. Porphyrin, a common organic molecule, is …