Photochemistry and astrochemistry: Photochemical pathways to interstellar complex organic molecules

KI Öberg - Chemical reviews, 2016 - ACS Publications
The interstellar medium is characterized by a rich and diverse chemistry. Many of its
complex organic molecules are proposed to form through radical chemistry in icy grain …

Photochirogenesis: Photochemical models on the absolute asymmetric formation of amino acids in interstellar space

C Meinert, P De Marcellus… - Physics of life …, 2011 - Elsevier
Proteins of all living organisms including plants, animals, and humans are made up of amino
acid monomers that show identical stereochemical l-configuration. Hypotheses for the origin …

JWST Observations of Young protoStars (JOYS+): Detecting icy complex organic molecules and ions-I. CH4, SO2, HCOO−, OCN−, H2CO, HCOOH, CH3CH2OH …

WRM Rocha, EF van Dishoeck, ME Ressler… - Astronomy & …, 2024 - aanda.org
Context. Complex organic molecules (COMs) are ubiquitously detected in the gas phase
and thought to be mostly formed on icy grains. Nevertheless, there have not been any …

Understanding the Molecular Kinetics and Chemical Equilibrium Phase of Frozen CO during Bombardment by Cosmic Rays by Employing the PROCODA Code

S Pilling, GA Carvalho, HA de Abreu… - The Astrophysical …, 2023 - iopscience.iop.org
Within the cold regions of space, ices that are enriched with carbon monoxide (CO)
molecules are exposed to ionizing radiation, which triggers new reactions and desorption …

Chemical Evolution of CO2 Ices under Processing by Ionizing Radiation: Characterization of Nonobserved Species and Chemical Equilibrium Phase with the …

S Pilling, GA Carvalho, WRM Rocha - The Astrophysical Journal, 2022 - iopscience.iop.org
Astrophysical ices are being exposed to ionizing radiation in space environments, which
trigger new reactions and desorption processes. In the lab, such processing by radiation has …

Conformer-dependent vacuum ultraviolet photodynamics and chiral asymmetries in pure enantiomers of gas phase proline

R Hadidi, DK Božanić, H Ganjitabar… - Communications …, 2021 - nature.com
Proline is a unique amino-acid, with a secondary amine fixed within a pyrrolidine ring
providing specific structural properties to proline-rich biopolymers. Gas-phase proline …

Characterization of acetonitrile ice irradiated by X-rays employing the procoda code – I. Effective rate constants and abundances at chemical equilibrium

GA Carvalho, S Pilling… - Monthly Notices of the …, 2022 - academic.oup.com
In this work, the chemical evolution of pure acetonitrile ice at 13 K irradiated with broad-band
soft X-rays (from 6 eV to 2 keV) is determined by using a computational methodology …

Mapping the evolution of pure CO2 ices irradiated by ions, UV, and electrons using the upgraded PROCODA code (employing an effective rate constant ordering by …

S Pilling, WRM Rocha, GA Carvalho… - Advances in Space …, 2023 - Elsevier
Chemical reactions and desorption processes are being triggered by incoming ionizing
radiation over astrophysical ices in cold space environments. The quantification of these …

Stability of amino acids and their oligomerization under high-pressure conditions: implications for prebiotic chemistry

T Otake, T Taniguchi, Y Furukawa, F Kawamura… - Astrobiology, 2011 - liebertpub.com
The polymerization of amino acids leading to the formation of peptides and proteins is a
significant problem for the origin of life. This problem stems from the instability of amino …

The influence of crystallinity degree on the glycine decomposition induced by 1 MeV proton bombardment in space analog conditions

S Pilling, LAV Mendes, V Bordalo, CFM Guaman… - Astrobiology, 2013 - liebertpub.com
Glycine is the simplest proteinaceous amino acid and is present in all life-forms on Earth. In
aqueous solutions, it appears mainly as zwitterion glycine (+ NH3CH2COO−); however, in …