Photoelectrochemical Proton-Coupled Electron Transfer of TiO2 Thin Films on Silicon

HS Nedzbala, D Westbroek… - Journal of the …, 2024 - ACS Publications
TiO2 thin films are often used as protective layers on semiconductors for applications in
photovoltaics, molecule–semiconductor hybrid photoelectrodes, and more. Experiments …

Recent Advances in Immobilizing and Benchmarking Molecular Catalysts for Artificial Photosynthesis

L Wang, M Shao, ZL Xie, KL Mulfort - Langmuir, 2024 - ACS Publications
Transition metal complexes have been widely used as catalysts or chromophores in artificial
photosynthesis. Traditionally, they are employed in homogeneous settings. Despite their …

Methyl Termination of p-Type Silicon Enables Selective Photoelectrochemical CO2 Reduction by a Molecular Ruthenium Catalyst

GP Bein, MA Stewart, EA Assaf, SJ Tereniak… - ACS Energy …, 2024 - ACS Publications
Methyl-terminated p-type silicon photoelectrodes selectively drive CO2 reduction by a
homogeneous [Ru (tpy)(Mebim-py)(NCCH3)] 2+ catalyst (tpy= 2, 2′: 6′, 2 ″-terpyridine …

Direct Detection of Key Intermediates during the Product Release in Rhenium Bipyridine-Catalyzed CO2 Reduction Reaction

S Chattopadhyay, MH Cheah, R Lomoth… - ACS …, 2024 - ACS Publications
Rhenium bipyridine tricarbonyl complexes, fac-[Re (bpy)(CO) 3X] n+, are highly effective in
selectively converting CO2 to CO under electrochemical and photochemical conditions …

Linear Free Energy Relationships Associated with Hydride Transfer From [(6,6′-R2-bpy)Re(CO)3H]: A Cautionary Tale in Identifying Hydrogen Bonding Effects in …

MR Elsby, A Kumar, LM Daniels, MZ Ertem… - Inorganic …, 2024 - ACS Publications
Six rhenium hydride complexes,[(6, 6′-R2-bpy) Re (CO) 3H](bpy= 2, 2′-bipyridine, R=
OEt, OMe, NHMe, Me, F, Br), were synthesized. These complexes insert CO2 to form …

Kinetic Isotope Effects and the Mechanism of CO2 Insertion into the Metal-Hydride Bond of fac-(bpy)Re(CO)3H

M Barakat, S Elhajj, R Yazji, AJM Miller… - Inorganic …, 2024 - ACS Publications
The 1, 2-insertion reaction of CO2 into metal–hydride bonds of d6-octahedral complexes to
give κ1-O-metal-formate products is the key step in various CO2 reduction schemes and as …

Oxidation Temperature-Dependent Electrochemical Doping of WO3 Deposited via Atomic Layer Deposition

ARC Bredar, HRM Margavio, C Donley… - The Journal of …, 2024 - ACS Publications
Silicon-based photoelectrochemical devices show promise for the performance of light-
driven CO2 reduction but suffer from instability under photoelectrochemical conditions …

Tricarbonyl rhenium (i) complexes with 8-hydroxyquinolines: structural, chemical, antibacterial, and anticancer characteristics

K Łyczko, A Pogorzelska, U Częścik, M Koronkiewicz… - RSC …, 2024 - pubs.rsc.org
Twelve tricarbonyl rhenium (I) complexes in the '2+ 1'system with the anionic bidentate N, O-
donor ligand (deprotonated 8-hydroxyquinoline (HQ) or its 2-methyl (MeHQ) or 5-chloro …

Quinoline-and coumarin-based ligands and their rhenium (I) tricarbonyl complexes: synthesis, spectral characterization and antiproliferative activity on T-cell …

M Piškor, I Ćorić, B Perić, KM Špoljarić, SI Kirin… - Journal of inorganic …, 2025 - Elsevier
Abstract Novel 6-substituted 2-(trifluoromethyl) quinoline 5a–5e and coumarin 6a–6d
ligands with aldoxime ether linked pyridine moiety were synthesized by O-alkylation of …