Ultrafast elementary photochemical processes of organic molecules in liquid solution

T Kumpulainen, B Lang, A Rosspeintner… - Chemical …, 2017 - ACS Publications
Ultrafast photochemical reactions in liquids occur on similar or shorter time scales compared
to the equilibration of the optically populated excited state. This equilibration involves the …

Pyridinium N-Phenolate Betaine Dyes

VG Machado, RI Stock, C Reichardt - Chemical reviews, 2014 - ACS Publications
It is well-known that the solvent can strongly influence the course, rate, and equilibrium
position of many chemical reactions. 1, 2 The position and intensity of the bands in the …

Solvatochromic dyes as solvent polarity indicators

C Reichardt - Chemical reviews, 1994 - ACS Publications
I. Scope This review compiles positively and negatively solvatochromic compounds which
have been usedto establish empirical scales of solvent polarity by means of UV/vis/near-IR …

Electron transfer from isolated molecules to biomolecules

M Bixon, J Jortner - Advances in Chemical Physics (Wiley, New …, 1999 - books.google.com
The genesis of the exploration of electron transfer (ET) in the condensed phase dates back
to the origins of chemistry in the nineteenth century. In 1808 Humphry Davy observed [1] that …

Auger-assisted electron transfer from photoexcited semiconductor quantum dots

H Zhu, Y Yang, K Hyeon-Deuk, M Califano, N Song… - Nano …, 2014 - ACS Publications
Although quantum confined nanomaterials, such as quantum dots (QDs) have emerged as a
new class of light harvesting and charge separation materials for solar energy conversion …

Vibrational modes and the dynamic solvent effect in electron and proton transfer

PF Barbara, GC Walker, TP Smith - Science, 1992 - science.org
This article primarily reviews recent work on ultrafast experiments on excited state
intramolecular electron and proton transfer, with an emphasis on experiments on chemical …

Dynamic solvent effects on electron‐transfer reactions

H Heitele - Angewandte Chemie International Edition in English, 1993 - Wiley Online Library
Electron‐transfer processes in solution are among the most important reactions in chemistry
and biology. The huge number of redox reactions of transition metal ions and complexes …

Lifetimes for radiative charge recombination in donor-acceptor molecules

M Bixon, J Jortner, JW Verhoeven - Journal of the American …, 1994 - ACS Publications
In this paper we demonstrate that the marked solvent dependence of the rates k „¿ for
radiative recombination in some donor (D)-bridge (B)-acceptor (A) molecules, which …

Fast responses from ''slowly relaxing''liquids: A comparative study of the femtosecond dynamics of triacetin, ethylene glycol, and water

YJ Chang, EW Castner Jr - The Journal of chemical physics, 1993 - pubs.aip.org
We have measured the ultrafast solvent relaxation of liquid ethylene glycol, triacetin, and
water by means of femtosecond polarization spectroscopy, using optical‐heterodyne …

Modeling of ultrafast electron-transfer processes: Validity of multilevel Redfield theory

D Egorova, M Thoss, W Domcke… - The Journal of chemical …, 2003 - pubs.aip.org
The capability of multilevel Redfield theory to describe ultrafast photoinduced electron-
transfer reactions is investigated. Adopting a standard model of photoinduced electron …