Broadening the scope of biocatalysis in sustainable organic synthesis

RA Sheldon, D Brady - ChemSusChem, 2019 - Wiley Online Library
This Review is aimed at synthetic organic chemists who may be familiar with organometallic
catalysis but have no experience with biocatalysis, and seeks to provide an answer to the …

Biocatalysis in organic chemistry and biotechnology: past, present, and future

MT Reetz - Journal of the American Chemical Society, 2013 - ACS Publications
Enzymes as catalysts in synthetic organic chemistry gained importance in the latter half of
the 20th century, but nevertheless suffered from two major limitations. First, many enzymes …

The limits to biocatalysis: pushing the envelope

RA Sheldon, D Brady - Chemical communications, 2018 - pubs.rsc.org
In the period 1985 to 1995 applications of biocatalysis, driven by the need for more
sustainable manufacture of chemicals and catalytic,(enantio) selective methods for the …

Using enzymes to tame nitrogen-centred radicals for enantioselective hydroamination

Y Ye, J Cao, DG Oblinsky, D Verma, CK Prier… - Nature …, 2023 - nature.com
The formation of C–N bonds—of great importance to the pharmaceutical industry—can be
facilitated enzymatically using nucleophilic and nitrene transfer mechanisms. However …

Chemoenzymatic dynamic kinetic resolution: a powerful tool for the preparation of enantiomerically pure alcohols and amines

O Verho, JE Bäckvall - Journal of the American Chemical …, 2015 - ACS Publications
Chemoenzymatic dynamic kinetic resolution (DKR) constitutes a convenient and efficient
method to access enantiomerically pure alcohol and amine derivatives. This Perspective …

Biocatalytic approaches to the synthesis of enantiomerically pure chiral amines

D Ghislieri, NJ Turner - Topics in Catalysis, 2014 - Springer
Enantiomerically pure chiral amines are valuable building blocks for the synthesis of
pharmaceutical drugs and agrochemicals. Indeed it is estimated that currently 40% of …

[引用][C] Green Chemistry and Catalysis

RA Sheldon - 2007 - books.google.com
This first book to focus on catalytic processes from the viewpoint of green chemistry presents
every important aspect:? Numerous catalytic reductions and oxidations methods? Solid-acid …

Borrowing hydrogen in the activation of alcohols

MHSA Hamid, PA Slatford… - Advanced Synthesis & …, 2007 - Wiley Online Library
Alcohols can be temporarily converted into carbonyl compounds by the metal‐catalysed
removal of hydrogen. The carbonyl compounds are reactive in a wider range of …

Discovery, applications, and catalytic mechanisms of Shvo's catalyst

BL Conley, MK Pennington-Boggio, E Boz… - Chemical …, 2010 - ACS Publications
Shvo's catalyst is a cyclopentadienone-ligated ruthenium complex,{[Ph4 (η5-C4CO)] 2H]}
Ru2 (CO) 4 (µ-H)(1, Scheme 1), that is a generally useful catalyst for transfer hydrogenation …

[图书][B] Introduction to green chemistry

J Andraos, AS Matlack - 2022 - taylorfrancis.com
Interest in green chemistry and clean processes has grown so much in recent years that
topics such as fluorous biphasic catalysis, metal organic frameworks, and process …