Progress and perspectives beyond traditional RAFT polymerization

MD Nothling, Q Fu, A Reyhani… - Advanced …, 2020 - Wiley Online Library
The development of advanced materials based on well‐defined polymeric architectures is
proving to be a highly prosperous research direction across both industry and academia …

Role of external field in polymerization: mechanism and kinetics

YN Zhou, JJ Li, YY Wu, ZH Luo - Chemical reviews, 2020 - ACS Publications
The past decades have witnessed an increasing interest in developing advanced
polymerization techniques subjected to external fields. Various physical modulations, such …

PET-RAFT polymerization: Mechanistic perspectives for future materials

ML Allegrezza, D Konkolewicz - ACS Macro Letters, 2021 - ACS Publications
In the past decade, photochemistry has emerged as a growing area in organic and polymer
chemistry. Use of light to drive polymerization has advantages by imparting spatial and …

Tailoring polymer dispersity by mixing chain transfer agents in PET-RAFT polymerization

K Parkatzidis, NP Truong, MN Antonopoulou… - Polymer …, 2020 - pubs.rsc.org
Here we report a simple and versatile batch methodology to tailor polymer dispersity utilizing
PET-RAFT polymerization. By mixing two chain transfer agents (CTAs) possessing different …

Remarkably Enhanced Luminol/H2O2 Chemiluminescence with Excellent Peroxidase-like Activity of FeCoNi-based Metal-Organic Xerogels for the Sensitive …

F Liu, S Xia, AMA Alboull, Z Dong, H Liu… - Analytical …, 2023 - ACS Publications
Metal-organic gels (MOGs) are a category of metal-organic smart soft materials with large
specific surface areas, loose porous structures, and open metal active sites. In this work …

Starlike polymer brush-based ultrasmall nanoparticles with simultaneously improved NIR-II fluorescence and blood circulation for efficient orthotopic glioblastoma …

S Chen, H Miao, X Jiang, P Sun, Q Fan, W Huang - Biomaterials, 2021 - Elsevier
Fluorescence imaging (FI) in the second near-infrared region (NIR-II, 1000–1700 nm) has
attracted great attention for brain tumor imaging due to its deep penetration and high …

Photons and photocatalysts as limiting reagents for PET-RAFT photopolymerization

B Parnitzke, T Nwoko, KGE Bradford… - Chemical Engineering …, 2023 - Elsevier
The kinetics of photoinduced electron/energy transfer-reversible addition fragmentation
chain transfer (PET-RAFT) polymerization were investigated using a model system of methyl …

NIR-II dye-based multifunctional telechelic glycopolymers for NIR-IIa fluorescence imaging-guided stimuli-responsive chemo-photothermal combination therapy

S Chen, B Sun, H Miao, G Wang, P Sun, J Li… - ACS Materials …, 2020 - ACS Publications
Optical imaging-guided chemo-photothermal combination therapy of cancers has attracted
considerable attention, because of its capacity for personalized, precision treatment and its …

A dual-modality hydrogen sulfide-specific probe integrating chemiluminescence with NIR fluorescence for targeted cancer imaging

X Dong, L Sun, Z Zhang, T Zhu, J Sun, J Gao… - Science China …, 2023 - Springer
Taking apart in numerous physiological and pathological activities, hydrogen sulfide (H2S)
has been selected as an excellent target spot for the early diagnosis of cancer. So far, there …

Ultrahigh-Molecular-Weight Triblock Copolymers via Inverse Miniemulsion Photoiniferter Polymerization

ME Lott, L Trachsel, E Schué, CLG Davidson IV… - …, 2024 - ACS Publications
We report the successful synthesis of ultrahigh-molecular-weight (UHMW, 106–107 g/mol)
ABA triblock copolymers through photoiniferter polymerization using solution and inverse …