The history of the Point Defect Model for the passive state: A brief review of film growth aspects

DD Macdonald - Electrochimica Acta, 2011 - Elsevier
A review is presented of the history of the Point Defect Model (PDM) for the growth and
breakdown of passive films that form on the surfaces of reactive metals in contact with …

Role of thiosulfate in the corrosion of steels: a review

L Choudhary, DD Macdonald, A Alfantazi - Corrosion, 2015 - meridian.allenpress.com
Thiosulfate salts have been known to be dangerous corrosion promoters for over 30 y, when
present under typical service conditions. This paper reviews the role of thiosulfate anion in …

Impedance Spectroscopy: Theory, Experiment, and Applications, Edited by Evgenij Barsoukov (Texas Instruments Inc.) and J. Ross Macdonald (University of North …

TM Nahir - 2005 - ACS Publications
The maiden volume of the much anticipated Springer serial, ReViews in Fluorescence,
showcases some of the latest advances in the field of fluorescence. This volume, divided …

Passivation of a corrosion resistant high entropy alloy in non-oxidizing sulfate solutions

KF Quiambao, SJ McDonnell, DK Schreiber, AY Gerard… - Acta materialia, 2019 - Elsevier
The passivation behavior of a novel high entropy alloy (HEA) of composition 38Ni-21Cr-
20Fe-13Ru-6Mo-2W at.%(33Ni-16Cr-17Fe-19Ru-9Mo-6W wt.%) was investigated in sulfate …

Point defect model for the corrosion of steels in supercritical water: Part I, film growth kinetics

Y Li, DD Macdonald, J Yang, J Qiu, S Wang - Corrosion Science, 2020 - Elsevier
Abstract A Point Defect Model has been developed to describe theoretically the corrosion of
metals and alloys in supercritical aqueous systems. The model, SCW_PDM, accounts for the …

Aqueous passivation of multi-principal element alloy Ni38Fe20Cr22Mn10Co10: Unexpected high Cr enrichment within the passive film

AY Gerard, J Han, SJ McDonnell, K Ogle, EJ Kautz… - Acta Materialia, 2020 - Elsevier
The aqueous passivation of a non-equiatomic Ni 38 Fe 20 Cr 22 Mn 10 Co 10-at.%(Ni 40 Fe
20 Cr 20 Mn 10 Co 10-wt.%) multi-principal element alloy (MPEA) was investigated in 0.1 M …

The semiconducting properties of passive films formed on AISI 316 L and AISI 321 stainless steels: A test of the point defect model (PDM)

A Fattah-Alhosseini, F Soltani, F Shirsalimi, B Ezadi… - Corrosion …, 2011 - Elsevier
The semiconductor properties of passive films formed on AISI 316L in 1M H2SO4 in three
temperatures and AISI 321 in 0.5 M H2SO4 were studied by employing Mott–Schottky …

Effect of solution concentration on semiconducting properties of passive films formed on austenitic stainless steels

A Fattah-Alhosseini, MA Golozar, A Saatchi, K Raeissi - Corrosion Science, 2010 - Elsevier
The semiconductor properties of passive films formed on AISI 316L in three acidic solutions
were studied by employing Mott–Schottky analysis in conjunction with the point defect model …

On the existence of our metals-based civilization: I. Phase-space analysis

DD Macdonald - Journal of the Electrochemical Society, 2006 - iopscience.iop.org
The stability of the barrier layers of bilayer passive films that form on metal and alloy
surfaces, when in contact with oxidizing aqueous environments, is explored within the …

Insights into the passivity and electrochemistry of CoCrFeMnNi high entropy alloy fabricated by underwater laser direct metal deposition

M Chen, Z Jia, Z Wang, C Xiang, J Pu, G Sun, EH Han - Corrosion Science, 2024 - Elsevier
Underwater laser direct metal deposition (UDMD) was employed to deposit CoCrFeMnNi
High entropy alloy. The deposition layer exhibits a homogeneous microstructure with …