How to rationally design homogeneous catalysts for efficient CO2 electroreduction?
Electrified converting CO 2 into valuable fuels and chemicals using a homogeneous
electrochemical CO 2 reduction (CO 2 ER) approach simplifies the operation, providing a …
electrochemical CO 2 reduction (CO 2 ER) approach simplifies the operation, providing a …
Fast Catalysis at Low Overpotential: Designing Efficient Dicationic Re(bpy2+)(CO)3I Electrocatalysts for CO2 Reduction
We report a series of isomeric, dicationic Re (bpy2+)(CO) 3I complexes with bpy (2, 2′-
bipyridine) modified by two phenyl-CH2-(NMe3)+ pendants with cations located at variable …
bipyridine) modified by two phenyl-CH2-(NMe3)+ pendants with cations located at variable …
Pincer shaped N-Mesoionic Pyridylidene Amide (PYA) for palladium catalyzed CO2 reduction
Abstract Palladium complexes (4-6) bearing mesoionic N-donor pyridylidene amide ligands
(PYAs) with different pendant groups of varying size and electronic properties were …
(PYAs) with different pendant groups of varying size and electronic properties were …
A Dicationic fac-Re(bpy)(CO)3Cl for CO2 Electroreduction at a Reduced Overpotential
A dicationic Re bipyridine-type complex, fac-Re (6, 6′-(2-((trimethylammonio)-methyl)
phenyl)-2, 2′-bipyridine)(CO) 3Cl hexafluorophosphate (1 2+), has been synthesized, and …
phenyl)-2, 2′-bipyridine)(CO) 3Cl hexafluorophosphate (1 2+), has been synthesized, and …
The Best of Both Worlds: Combining the Power of MICs and WCAs To Generate Stable and Crystalline CrI‐Tetracarbonyl Complexes with π‐Accepting Ligands
T Bens, RRM Walter, J Beerhues… - … A European Journal, 2023 - Wiley Online Library
Here we present stable and crystalline chromium (I) tetracarbonyl complexes with pyridyl‐
MIC (MIC= mesoionic carbene) ligands and weakly coordinating anions (WCA=[Al (ORF) …
MIC (MIC= mesoionic carbene) ligands and weakly coordinating anions (WCA=[Al (ORF) …
CO2 Activation with Manganese Tricarbonyl Complexes through an H‐Atom Responsive Benzimidazole Ligand
Herein, we report the synthesis and characterization of two manganese tricarbonyl
complexes, MnI (HL)(CO) 3Br (1 a‐Br) and MnI (MeL)(CO) 3Br (1 b‐Br)(where HL= 2‐(2' …
complexes, MnI (HL)(CO) 3Br (1 a‐Br) and MnI (MeL)(CO) 3Br (1 b‐Br)(where HL= 2‐(2' …
Effect of Variable Amine Pendants in the Secondary Coordination Sphere of Manganese Bipyridine Complexes on the Electrochemical CO2 Reduction
The increasing concentration of CO2 in the atmosphere and its impact on the climate are
matters of significant concern. Extensive research is being conducted on molecular catalysts …
matters of significant concern. Extensive research is being conducted on molecular catalysts …
Structure Activity Relationships for Second‐Coordination Sphere Functional Group Dependent CO2 Reduction by Manganese Bipyridyl Electrocatalysts
V Blasczak, A Murphy, L Suntrup, KT Ngo… - …, 2024 - Wiley Online Library
A series of twelve second coordination sphere (SCS) functionalized manganese tricarbonyl
bipyridyl complexes are investigated for their electrocatalytic CO2 reduction properties in …
bipyridyl complexes are investigated for their electrocatalytic CO2 reduction properties in …
Calix[8]arene‐Based Manganese Complexes for Electrocatalytic CO2 Reduction
A Berlanga‐Vázquez, I Castillo - Israel Journal of Chemistry, 2024 - Wiley Online Library
Transition metal catalysts with modified second‐coordination sphere employed in the
electrocatalytic CO2 can result in increased activity or directed product selectivity …
electrocatalytic CO2 can result in increased activity or directed product selectivity …
CO2 Reduction with High Bulk Turnover Numbers at Small Overpotentials by a fac-Mn (bpy)(CO) 3L Complex with a Redox-Active, Electron Reservoir Ligand
A Galvez-Rodriguez, O Martinez-Perez, SH Bergens - 2025 - researchsquare.com
The electrocatalytic CO 2 reduction reaction (CRR) is required to convert CO 2 into useful
commodity chemicals with renewable energy thereby reducing global greenhouse gas …
commodity chemicals with renewable energy thereby reducing global greenhouse gas …