C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

The construction of carbon–carbon bonds is a central tenet of modern synthetic chemistry.
Metal-catalyzed C–H functionalization can serve as a particularly powerful tool for achieving …

Silver, known and utilized since ancient times, is a coinage metal, which has been widely
used for various organic transformations in the past few decades. Currently, the silver …

The insertion of carbenes into the α-C–H bonds of ethers represents one of the most
powerful approaches to access polysubstituted α-branched ethers. However, intermolecular …

Alkanes are an abundant and valuable resource for transformation into value-added fine
chemicals. However, selective functionalization of specific C (sp 3)–H bonds in alkanes for …

Transition-metal-catalyzed transfer of a carbene group from diazo compounds has great
significance in the field of organic synthesis by allowing access to valuable chemicals from …

The direct functionalization of low reactive C (sp3)–H and C (sp2)–H bonds of alkanes and
arenes, respectively, by metal-induced carbene transfer from diazo compounds is reviewed …

The recent development of intermolecular C–H insertion in the application of C (sp 3)–H
bond functionalizations, especially for light alkanes, is reviewed. The challenging problem of …

Cobalt( i )-catalysed CH-alkylation of terminal olefins, and beyond - Chemical Communications
(RSC Publishing) DOI:10.1039/C5CC07363D Royal Society of Chemistry View PDF …

The copper complex Tp (CF3) 2, BrCu (NCMe)(1, Tp (CF3) 2, Br= hydrotris ((3, 5-bis
(trifluoromethyl)-4-bromo)-pyrazol-1-yl) borate) catalyzes the insertion of the CHCO2Et …