Electronic structure of corrole derivatives: insights from molecular structures, spectroscopy, electrochemistry, and quantum chemical calculations

A Ghosh - Chemical Reviews, 2017 - ACS Publications
Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

Strategies for corrole functionalization

JFB Barata, MGPMS Neves, MAF Faustino… - Chemical …, 2017 - ACS Publications
This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

Electrochemistry of corroles in nonaqueous media

Y Fang, Z Ou, KM Kadish - Chemical Reviews, 2017 - ACS Publications
This review describes the known electrochemistry of corroles in nonaqueous media from
1980 until the present. The outline of the review is grouped according to the periodic table …

Milestones and most recent advances in Corrole's Science and Technology

A Mahammed, Z Gross - Journal of the American Chemical …, 2023 - ACS Publications
The renaissance in corrole chemistry is strongly correlated with synthetic breakthroughs that
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …

The story of 5d metallocorroles: from metal–ligand misfits to new building blocks for cancer phototherapeutics

AB Alemayehu, KE Thomas, RF Einrem… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus Porphyrin chemistry is Shakespearean: over a century of study has not withered
the field's apparently infinite variety. Heme proteins continually astonish us with novel …

Seven clues to ligand noninnocence: the metallocorrole paradigm

S Ganguly, A Ghosh - Accounts of Chemical Research, 2019 - ACS Publications
Conspectus Noninnocent ligands do not allow an unambiguous definition of the oxidation
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …

Rhenium chemistry–then and now

JR Dilworth - Coordination Chemistry Reviews, 2021 - Elsevier
The first section provides a background to the whole review. The second presents a
historical perspective of fundamental developments in rhenium chemistry from its discovery …

Gold tris (carboxyphenyl) corroles as multifunctional materials: room temperature near-ir phosphorescence and applications to photodynamic therapy and dye …

AB Alemayehu, NU Day, T Mani… - … Applied Materials & …, 2016 - ACS Publications
Two amphiphilic corroles 5, 10, 15-tris (3-carboxyphenyl) corrole (H3 [m TCPC]) and 5, 10,
15-tris (4-carboxyphenyl) corrole (H3 [p TCPC]) and their gold complexes have been …

X-ray absorption spectroscopy as a probe of ligand noninnocence in metallocorroles: the case of copper corroles

H Lim, KE Thomas, B Hedman, KO Hodgson… - Inorganic …, 2019 - ACS Publications
The question of ligand noninnocence in Cu corroles has long been a topic of discussion.
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …

Chelators and metal complex stability for radiopharmaceutical applications

NC Okoye, JE Baumeister, F Najafi Khosroshahi… - Radiochimica …, 2019 - degruyter.com
Diagnostic and therapeutic nuclear medicine relies heavily on radiometal nuclides. The
most widely used and well-known radionuclide is technetium-99m (99mTc), which has …