Context. Many molecules observed in the interstellar medium are thought to result from the
thermal desorption of ices. Parameters such as the desorption energy and pre-exponential …

One of the ultimate goals of chemistry is to understand and manipulate chemical reactions,
which implies the ability to monitor the reaction and its underlying mechanism at an atomic …

Aldehydes are ubiquitous in star-forming regions and carbonaceous chondrites, serving as
essential intermediates in metabolic pathways and molecular mass growth processes to vital …

Methanesulfenic acid, CH3SOH, is a fleeting intermediate in the· OH-initiated oxidation
reactions of dimethyl sulfide (DMS) and dimethyl disulfide (DMDS) in the atmosphere …

Context. Carbonyl sulfide (OCS) is widely observed in the gas phase toward star-forming
regions and was the first of the only two sulfur-bearing species to be detected in interstellar …

Enols–tautomers of ketones or aldehydes–are anticipated to be ubiquitous in the interstellar
medium and play a key role in the formation of complex organic molecules in deep space …

Ketoaldehydes are key intermediates in biochemical processes including carbohydrate,
lipid, and amino acid metabolism. Despite their crucial role in the interstellar synthesis of …

The astrochemically relevant reactions of [H, C, N, S] isomers were studied both theoretically
and experimentally. The energetics and barriers of H-atom-addition and H-atom-abstraction …

Ralf I. Kaiser replied: So far, the phenylethynyl radical has not been detected in the
interstellar medium. However, this does not mean that it is not present. The phenylethynyl …

The rotational spectrum of the syn conformer of thiobenzoic acid (C 6 H 5 COSH) has been
observed by Fourier transform microwave spectroscopy in a supersonic jet. Spectra of all …