Cyclobutarenes and related compounds

AK Sadana, RK Saini, WE Billups - Chemical reviews, 2003 - ACS Publications
Due to the thermodynamic stability associated with the aromatic system and the kinetic
reactivity of the strained cyclobutene ring, the cyclobutarenes represent a unique class of …

Recent chemistry of benzocyclobutenes

G Mehta, S Kotha - Tetrahedron, 2001 - Elsevier
The bicyclo [4.2. 0] octa-1, 3, 5-triene 1, often referred to (incorrectly) in the literature as
benzocyclobutene (BCB), and its derivatives have a long and interesting history. 1 BCB 1 …

Acetohydrazone: A Transient Directing Group for Arylation of Unactivated C(sp3)–H Bonds

F Ma, M Lei, L Hu - Organic letters, 2016 - ACS Publications
A straightforward and efficient method has been developed for the synthesis of 2-
benzylbenzaldehyde derivatives from 2-methylbenzaldehyde and iodobenzene via a C …

Semicarbazide: A Transient Directing Group for C(sp3)−H Arylation of 2‐Methylbenzaldehydes

F Wen, Z Li - Advanced Synthesis & Catalysis, 2020 - Wiley Online Library
Semicarbazide as an effective transient directing group for C (sp3)− H arylation of 2‐
methylbenzaldehydes is described. Various substituted 2‐benzylbenzaldehydes are …

Carbenes and Carbenoids in Synthesis of Heterocycles

AF Khlebnikov, MS Novikov, RR Kostikov - Advances in heterocyclic …, 1996 - Elsevier
The primary purpose of this review is to summarize the ongoing utility of carbenes in
heterocyclic synthesis. Several excellent reviews on the synthetic aspects of carbene …

CYCLOADDITIONS OF ortho-QUINODIMETHANES DERIVED FROM BENZOCYCLOBUTENES IN ORGANIC SYNTHESIS. A REVIEW

PY Michellys, H Pellissier, M Santelli - Organic preparations and …, 1996 - Taylor & Francis
A number of natural products like steroids, alkaloids and some antibiotics exhibit
complicated polycyclic structures. Their synthesis require stereoselective cyclization …

Blitzvakuumpyrolyse von o‐Alkylaryl‐und Arylalkylchlorboranen Synthese benzoanellierter Boracycloalkene

W Schacht, D Kaufmann - Chemische Berichte, 1987 - Wiley Online Library
Abstract Die als Pyrolyse‐Edukte eingesetzten Dichlororganylborane wurden durch
Umsetzung der entsprechenden Triorganylboroxine und Aryltrimethylsilane (zu 3, 4) oder …

Glycinamide hydrochloride as a transient directing group: Synthesis of 2-benzylbenzaldehydes by C(sp3)−H arylation

F Wen, Z Li - Synthetic Communications, 2020 - Taylor & Francis
Glycinamide hydrochloride as an inexpensive and commercially available transient directing
group for the C (sp3)− H arylation of 2-methylbenzaldehydes is described. A series of …

Flash vacuum pyrolysis of benzylidene halides, benzotrihalides and aryl halides over magnesium

RA Aitken, PKG Hodgson, AO Oyewale - Journal of analytical and applied …, 2017 - Elsevier
Flash vacuum pyrolysis at 600° C through glass wool coated with freshly sublimed
magnesium is examined as a preparative method for dehalogenative coupling in organic …

Dehalogenation of organic halides by flash vacuum pyrolysis over magnesium: a versatile synthetic method

R áAlan Aitken, PKG Hodgson… - Chemical …, 1997 - pubs.rsc.org
Dehalogenation of organic halides by flash vacuum pyrolysis over magnesium: a versatile
synthetic method Page 1 + 4 5 RC6H4CH2X RC6H4CH2CH2C6H4R + RC6H4Me 2 3 (R …