Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …

This Minireview describes recent advances of organophosphorus compounds as opto‐
electronic materials in the field of organic electronics. The progress of (hetero‐) phospholes …

Neutral stibinyl and bismuthinyl radicals are typically short-lived, reactive species. Here we
show the synthesis and solid-state structures of two stable stibinyl [L (Cl) Ga] 2Sb· 1 and …

The review presents an overview of the organic radicals that have been designed and
synthesized recently, and their magnetic properties are discussed. The π-conjugated …

Reported herein is the first isolation of tetracyano‐naphthalenediimide [NDI (CN) 4] and its
radical anion, and structural elucidation through spectroscopic and X‐ray diffraction studies …

Abstract LGa (P2OC) cAAC 2 features a 1, 2‐diphospha‐1, 3‐butadiene unit with a
delocalized π‐type HOMO and a π*‐type LUMO according to DFT calculations.[LGa (P2OC) …

The search for main‐group element‐based radicals is one of the main research topics in
contemporary chemistry because of their fascinating chemical and physical properties. The …

We report the phospha-bora-Wittig reaction for the direct preparation of phosphaalkenes
from aldehydes, ketones, esters, or amides. The transient phosphaborene Mes* P═ B–NR2 …

We report on the structures of three unprecedented heteroleptic Sb‐centered radicals [L (Cl)
Ga](R) Sb.(2‐R, R= B [N (Dip) CH] 2 2‐B, 2, 6‐Mes2C6H3 2‐C, N (SiMe3) Dip 2‐N) …

Abstract Singlet cyclo‐1, 3‐dipnicta‐2, 4‐diazane‐1, 3‐diyls of the type [E (μ‐NTer) 2E](2,
E= P, As, Ter= 2, 6‐dimesitylphenyl) can undergo a one‐electron‐oxidation utilizing silver …