Despite being weak attractive forces, closed‐shell metallophilic interactions play important
roles in the Group 11 metal complexes on their diverse structural and physical features. A …

Excimers and exciplexes are defined as assemblies of atoms or molecules A/A′ where
interatomic/intermolecular bonding appears only in excited states such as [A2]*(for …

This review provides a comprehensive overview of the most recent progress in chemistry
and applications of metal complexes containing heteroallylic ligands such as amidinates …

We report the preparation and characterization of the dinuclear AuII hydroxide complex
AuII2 (L) 2 (OH) 2 (L= N, N′‐bis (2, 6‐dimethyl) phenylformamidinate) and study its …

A systematic theoretical study has been carried out on the visible light-mediated gold-
catalyzed oxyarylation of alkenes. The detailed mechanism of the dual Au and photoredox …

The construction of C–S bonds is of great importance in the field of synthetic and medicinal
chemistry. Herein, solvent-induced umpolung reactions from dioxygenation to interligand C …

Mononuclear gold (ii) complexes are very rare labile species. Transient gold (ii) species
have been suggested in homogeneous catalysis and in medical applications, but their …

A two‐way street! The two‐electron oxidation of a novel binuclear stibine gold compound
induces an umpolung of the Sb Au dative bond which switches from Sb→ Au in the …

Carbene and its analogous silylene and germylene ligated trinuclear gold complexes are
well established due to their cationic stability, but the anionic stability of such complexes is …

It remains a pressing task to search for new two-dimensional (2D) semiconducting materials
for future-generation electronic applications. By using density functional theory computations …